No Need for Rare Earths or Liquid Helium!
Cryogenic Cooling Material Composed Solely of Abundant Elements

— Holding Promise for Application to Cooling in Medical MRI and Quantum Computers —

2025.12.24

NIMS (National Institute for Materials Science)

In collaboration with the National Institute of Technology (KOSEN), Oshima College, the National Institute for Materials Science (NIMS) succeeded in developing a new regenerator material composed solely of abundant elements, such as copper, iron, and aluminum, that can achieve cryogenic temperatures (approx. 4 K = −269°C or below) without using any rare-earth metals or liquid helium. By utilizing a special property called "frustration" found in some magnetic materials, where the spins cannot simultaneously satisfy each other's orientations in a triangular lattice, the team demonstrated a novel method that replaces the conventional rare-earth-dependent cryogenic cooling technology. The developed material holds promise for responding to the lack of liquid helium as well as for application to stable cooling in medical magnetic resonance imaging (MRI) and quantum computers, which is expected to see further growth in demand. This research result was published in UK scientific journal, Scientific Reports, on December 22, 2025.

Abstract

Background

Cryogenic cooling technology that has primarily been used in medical MRI, etc. had a problem of being strongly dependent on liquid helium and rare-earth elements that are subject to supply instability and resource depletion concerns. For example, holmium, which is currently used in regenerator materials, has an annual production of only 100 tons and its reserves are unevenly distributed. Therefore, with the demand for cryogenic cooling expected to significantly increase in the future, there was a strong need to develop new cooling technology that does not depend on such scarce resources.

Key Findings

In this study, a joint research team from NIMS and the National Institute of Technology (KOSEN), Oshima College, succeeded in developing a regenerator material for mechanical coolers (Gifford-McMahon [GM] coolers) capable of cooling to cryogenic temperatures without using liquid helium, which contains no rare-earth metal elements and uses a material composed solely of abundant elements, such as copper, iron, and aluminum. The team demonstrated that the material exhibits high specific heat at cryogenic temperatures despite being transition metal, by utilizing an effect known as "frustration," specifically found in magnetic materials that have a special crystal structure called a triangular lattice, where the spin orientations become difficult to align until they reach cryogenic temperatures. The material achieved performance comparable to that of conventional cooling materials containing rare earths (holmium compounds). This was the first time that a magnetic regenerator material for coolers that does not use rare-earth elements showed practical-level performance.

Figure. In the 1960s, GM coolers used lead (Pb) as the cold storage material, but in the 1990s, the rare-earth metal compound HoCu2 was introduced, and the cooling performance dramatically improved. While the rare-earth-free cold storage material CuFe0.98Al0.02O2 (CFAO) developed in this study has a cooling capacity comparable to them, it leads to sustainable and environmentally friendly cryogenic cooling technologies as the material is composed solely of abundant elements.

Future Outlook

The cryogenic cooling material developed in this study uses abundant resources, making it highly sustainable and environmentally friendly. Therefore, it holds promise for application to cryogenic cooling in medical MRI and quantum computers, which is expected to see further growth in demand.

Other Information

  • This project was conducted by a research team consisting of Noriki Terada (Chief Researcher, Green Magnetic Materials Group (GMMG), Research Center for Magnetic and Spintronic Materials (CMSM), NIMS), Hiroaki Mamiya (Chief Researcher, GMMG, CMSM, NIMS), Akiko Saito (Chief Researcher, GMMG, CMSM, NIMS), and Shinji Masuyama (Professor, National Institute of Technology (KOSEN), Oshima College), as part of Japan Science and Technology Agency (JST) Adaptable and Seamless Technology Transfer Program through Target-driven R&D (A-STEP) "Development of regenerator materials for cryocoolers without rare-earth elements" (Principal Investigator: Noriki Terada).
  • This research result was published online in UK scientific journal, Scientific Reports, on December 22, 2025.

Published Paper

Title : Innovative Cryogenic Cooling Material Using Spin Frustration from Abundant Elements
Authors : Noriki Terada, Hiroaki Mamiya, Akiko T. Saito, and Shinji Masuyama
Journal : Scientific Reports
DOI : 10.1038/s41598-025-29709-5
Publication Date : December 22, 2025

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Contact information

Regarding This Research

Noriki Terada
Chief Researcher
Research Center for Magnetic and Spintronic Materials
National Institute for Materials Science
E-Mail: TERADA.Noriki=nims.go.jp (Please change "=" to "@")
TEL: +81-29-860-4627

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