第3回マテリアル基盤セミナー

2024年1月22日 (月) 15 : 00-16 : 00

千現地区　研究本館8階中セミナー室 (811・812室)
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Prof. Dr.Karl-Heinz Ernst
(Empa, Swiss Federal Laboratories for Materials Science and Technology)

Magneto-chiral selectivity in adsorption and electron transport of single helicene molecules on metal surfaces

Soon after his seminal discovery of molecular chirality Pasteur suggested physical fields as its origin and assumed that magnetic fields must be the source of chirality in the universe. Lord Kelvin refuted Pasteur's suggestions and made clear that magnetism has no chirality. In 1894, however, Pierre Curie proposed that parallel and antiparallel alignments of electric and magnetic fields will induce chirality, but such chiral influence must vanish under conditions of thermodynamic equilibrium. We report that single helical aromatic hydrocarbons, so-called helicenes, undergo enantioselective adsorption on ferromagnetic cobalt surfaces. Spin- and chirality sensitive scanning tunneling microscopy (STM) reveals that molecules of opposite handedness prefer adsorption onto cobalt islands with opposite out-of-plane magnetization. As mobility ceases in the final chemisorbed state, it is concluded that enantioselection must occur in a physisorbed transient precursor state. Such observation suggests electron spin-depend van-der-Waals forces. Simultaneous measurements of the tunneling current through both enantiomers on a given Co nanoisland yields a magneto-chiral specific conductance of up to 50% for single helicene molecules, thus refuting previously proposed ensemble effects as origin of the so-called chirality-induced spin selectivity (CISS). Our results open the opportunity towards new single-molecule spin-valve devices and shine light into the origin chirality-induced spin selectivity (CISS).
In the second part of the talk I will present a unique self-assembly phenomenon governed by entropy maximization and topological constraint as well as open-shell helicenes showing Kondo effects on different metallic surfaces.