原野 幸治 (はらの こうじ)
科研費・学術変革領域研究(A)「メゾヒエラルキーの物質科学」 領域HP・ X(旧Twitter)
(原野は計画班および広報を担当)
国立研究開発法人 物質・材料研究機構 マテリアル基盤研究センター 電子顕微鏡グループ 主幹研究員
東京工業大学 科学技術創成研究院 自律システム材料学研究センター 特定教授(Visiting Professor)
生年月日 1980年3月21日
学歴
1998年 3月 久留米大学附設高等学校卒業
2002年 3月 東京大学理学部化学科卒業
2004年 3月 東京大学大学院理学系研究科化学専攻 修士課程修了
2007年 3月 東京大学大学院理学系研究科化学専攻 博士課程終了(塩谷光彦教授)
博士(理学)取得(東京大学)
職歴
2004年 4月~2007年3月 日本学術振興会 特別研究員(DC1)
2007年 4月~6月 東北大学大学院理学研究科 博士研究員(山下正廣教授)
2007年 7月~2015年3月 東京大学大学院理学系研究科化学専攻 助教 (中村栄一教授)
2015年 4月~2022年1月 東京大学総括プロジェクト機構 特任准教授 (東京大学大学院理学系研究科化学専攻 兼務)
2022年 2月~ 現職
学会活動
2016年~ 日本化学会 有機結晶部会 広報委員
2017年~ 日本化学会 代表正会員
受賞
2004年 第54回錯体化学討論会 ポスター賞
2005年 日本化学会第85春季年会 学生講演賞
2005年 Tokyo Summer School on Frontier Chemistry 2005 ポスター賞
2009年 第25回 井上研究奨励賞
2012年 グローバルCOE 海外レクチャーシップ
2014年 日本化学会第94春季年会優秀講演賞(学術)
2015年 JST CREST「分子技術」ライジング・スター賞
2016年 第65回 日本化学会進歩賞
2016年 第9回 風戸研究奨励賞
2018年 Chemist Award BCA
2019年 Thieme Chemistry Journals Award
2019年 科学技術分野の文部科学大臣表彰 若手科学者賞
2019年 日本顕微鏡学会奨励賞
2020年 BCSJ賞(6月号)
2020年 第16回 野副記念奨励賞
2020年 BCSJ賞(9月号)
2021年 BCSJ賞(2月号)
2022年 第63回科学技術映像祭研究開発部門優秀賞
2023年 化学コミュニケーション賞2022 審査員特別賞(団体)
Publication List of Koji HARANO
Original publications :
79. Blue Shift of Localized Surface Plasmon Resonance of Gold Ultrathin Nanorod by Forming a Single Atomic Silver Shell via Antigalvanic Process, S. Maity, T. Komagata, S. Takano, S. Masuda, J. Kikkawa, K. Kimoto, K. Harano, T. Tsukuda, Nano Lett., ASAP.
78. Ion-Pairing Chromonic Liquid Crystals via Alternately Stacked Assembly of Amphiphilic Charged π-Electronic Systems, Y. Maruyama, K. Harano, H. Kanai, Y. Ishida, H. Tanaka, S. Sugiura, H. Maeda, Angew. Chem. Int. Ed., Accepted Article.
77. Pentagon-Rich Caged Carbon Catalyst for the Oxygen Reduction Reaction in Acidic Electrolytes, G. Chen, M. Isegawa. T. Koide, Y. Yoshida, K. Harano, K. Hayashida, S. Fujita, K. Takeyasu, K. Ariga, J. Nakamura, Angew. Chem. Int. Ed., Accepted Article.
76. Reduction-Induced Self-Propelled Oscillatory Motion of Perylenediimides on Water, L. R. Holstein, N. J. Suematsu, M. Takeuchi, K. Harano, T. Banno, A. Takai, Angew. Chem. Int. Ed., Accepted Article.
75. RhRu Bimetallic Oxide Cluster Catalysts for Cross-Dehydrogenative Coupling of Arenes and Carboxylic Acids, S. Hasegawa, K. Harano, K. Motokura, J. Am. Chem. Soc., 146, 19059–19069 (2024).
74. Ambipolar Charge-Trapping in Self-Assembled Nanostructures of Supramolecular Miktoarm Star-Shaped Copolymer with a Zinc Phthalocyanine Core, X. Zhong, D. Panigrahi, R. Hayakawa, Y. Wakayama, K. Harano, M. Takeuchi, J. Aimi, J. Mater. Chem. C., 12, 9642-9651 (2024).
73. Grinding-induced Water Solubility Exhibited by Mechanochromic Luminescent Supramolecular Fibers, Q. Liu, T. Zhang, Y. Ikemoto, Y. Shinozaki, G. Watanabe, Y. Hori, Y. Shigeta, T. Midorikawa, K. Harano, Y. Sagara, Small, 20, 2400063 (2024).
72. Diphosphine-Protected IrAu12 Superatom with Open Site(s): Synthesis and Programmed Stepwise Assembly, Y. Fukumoto, T. Omoda, H. Hirai, S. Takano, K. Harano, T. Tsukuda, Angew. Chem. Int. Ed., 63, e202402025 (2024).
71. Unsupervised Machine Learning Combined with 4D Scanning Transmission Electron Microscopy for Bimodal Nanostructural Analysis, K. Kimoto, J. Kikkawa, K. Harano, O. Cretu, Y. Shibasaki, F. Uesugi, Sci. Rep., 14, 2901 (2024).
70. Fast Electron Damage Mechanism of Epoxy Resin Studied by Electron Energy Loss Spectroscopy and Electron Diffraction, J. Kikkawa, A. Nii, Y. Sakaniwa, N. Kon, M. Sakamaki, T. Ohashi, N. Nita, K. Harano, K. Kimoto, J. Chem. Phys., 159, 174708 (2023).
69. Supramolecular Polymer Polymorphism: Spontaneous Helix-Helicoid Transition through Dislocation of Hydrogen-Bonded π-Rosettes, C. Otsuka, S. Takahashi, A. Isobe, T. Saito, T. Aizawa, R. Tsuchida, S. Yamashita, K. Harano, H. Hanayama, L. Liu, M. J. Hollamby, T. Ohkubo, S. Yagai, J. Am. Chem. Soc., 145, 22563-22576 (2023).
68. Au13 Superatom Bearing Two Terpyridines at Coaxial Positions: Photoluminescence Quenching via Complexation with 3d Metal Ions, N. Kito, S. Takano, S. Masuda, K. Harano, T. Tsukuda, Bull. Chem. Soc. Jpn., 96, 1045-1051 (2023).
67. Time-Resolved Imaging and Analysis of the Electron Beam-Induced Formation of an Open-Cage Metallo-Azafullerene, H. Hoelzel, S. Lee, K. Y. Amsharov, N. Jux, K. Harano, E. Nakamura, D. Lungerich, Nat. Chem., 15, 1444-1451 (2023).
66. Saturated Linkers in Two-Dimensional Covalent Organic Frameworks Boost their Luminescence, M. Yang, H. Hanayama, L. Fang, M. A. Addicoat, Y. Guo, R. Graf, K. Harano, J. Kikkawa, E. Jin, A. Narita, K. Müllen, J. Am. Chem. Soc., 145, 14417–14426 (2023).
65. Wavy Graphene-Like Network Forming during Pyrolysis of Polyacrylonitrile into Carbon Fiber, T. Ishikawa, F. Tanaka, K. Kurushima, A. Yasuhara, R. Sagawa, T. Fujita, R. Yonesaki, K. Iseki, T. Nakamuro, K. Harano, E. Nakamura, J. Am. Chem. Soc., 145, 12244–12254 (2023).
64. Defect Photoluminescence from Alkylated Boron Nitride Nanotubes, T. Shiraki, R. Saito, H. Sasaki, N. Tanaka, K. Harano, T. Fujigaya, Chem. Lett., 52, 44–47 (2023). (Selected as Editor's Choice and Cover Picture, open-access).
63. Synergistically Activated Pd Atom in Polymer-Stabilized Au23Pd1 Cluster, S. Hasegawa, S. Masuda, S. Takano, K. Harano, J. Kikkawa, T. Tsukuda, ACS Nano, 16, 16932–16940 (2022).
62. Time-resolved Atomistic Imaging and Statistical Analysis of Daptomycin Oligomers with and without Calcium Ion, T. Nakamuro, K. Kamei, K. Sun, J. W. Bode, K. Harano, E. Nakamura, J. Am. Chem. Soc., 144, 13612–13622 (2022). (ChemRxiv, DOI:10.26434/chemrxiv-2022-xdkxs)
61. Excited state modulation of C70 dimerization in a carbon nanotube under a variable electron acceleration voltage, D. Liu, D. Lungerich, T. Nakamuro, K. Harano, E. Nakamura, Micron, 160, 103316 (2022).
60. Time-Resolved Imaging of Stochastic Cascade Reactions over a Submillisecond to Second Time Range at the Angstrom Level, T. Shimizu, D. Lungerich, K. Harano, E. Nakamura, J. Am. Chem. Soc., 144, 9797–9805 (2022). (arXiv, 2202.13332)
59. Polymer-Stabilized Au38 Cluster: Atomically Precise Synthesis by Digestive Ripening and Characterization of Atomic Structure and Oxidation Catalysis, S. Hasegawa, S. Masuda, S. Takano, K. Harano, T. Tsukuda, ACS Catal., 12, 6550–6558 (2022).
58. Ionization and Electron Excitation of C60 in a Carbon Nanotube: A Variable Temperature/voltage Transmission Electron Microscopic Study, D. Liu, S. Kowashi, T. Nakamuro, D. Lungerich, K. Yamanouchi, K. Harano, E. Nakamura, Proc. Natl. Acad. Sci. U.S.A., 119, e2200290119 (2022).
57. Atomic-number (Z)-correlated Atomic Sizes for Deciphering Electron Microscopic Molecular Images, J. Xing, K. Takeuchi, K. Kamei, T. Nakamuro, K. Harano, E. Nakamura, Proc. Natl. Acad. Sci. U.S.A., 119, e2114432119 (2022). (Press release)
56. De Novo Synthesis of Free-Standing Flexible 2-D Intercalated Nanofilm Uniform over Tens of cm2, P. Ravat, H. Uchida, R. Sekine, K. Kamei, A. Yamamoto, O. Konovalov, M. Tanaka, T. Yamada, K. Harano, E. Nakamura, Adv. Mater., 34, 2106465 (2022).
55. A Singular Molecule-to-Molecule Transformation on Video: The Bottom-Up Synthesis of Fullerene C60 from Truxene Derivative C60H30, D. Lungerich, H. Hoelzel, K. Harano, N. Jux, K. Y. Amsharov, E. Nakamura, ACS Nano, 15, 12804–12814 (2021). (Selected as Supplementary Cover)
54. New Magic Au24 Cluster Stabilized by PVP: Selective Formation, Atomic Structure and Oxidation Catalysis, S. Hasegawa, S. Takano, K. Harano, T. Tsukuda, JACS Au, 1, 660–668 (2021). (Selected as Supplementary Cover, open access)
53. Rim Binding of Cyclodextrins in Size-Sensitive Guest Recognition, H. Hanayama, J. Yamada, I. Tomotsuka, K. Harano, E. Nakamura, J. Am. Chem. Soc., 143, 5786–5792 (2021).
52. Few-nm-sized, phase-pure Au5Sn intermetallic nanoparticles: synthesis and characterization, S. Osugi, S. Takano, S. Masuda, K. Harano, T. Tsukuda, Dalton Trans., 50, 5177-5183 (2021). (Selected as Hot Article)
51. Nano- and Microspheres Containing Inorganic and Biological Nanoparticles: Self-Assembly and Electron Tomographic Analysis, R. Sekine, P. Ravat, H. Yanagisawa, C. Liu, M. Kikkawa, K. Harano, E. Nakamura, J. Am. Chem. Soc., 143, 2822–2828 (2021).
50. Capturing the Moment of Emergence of Crystal Nucleus from Disorder, T. Nakamuro, M. Sakakibara, H. Nada, K. Harano, E. Nakamura, J. Am. Chem. Soc., 143, 1763–1767 (2021). (Highlighted in NHK news etc., open access)
49. Synthesis and Characterization of a Well-Defined Carbon Nanohorn-Supported Molybdenum Dioxo Catalyst by SMART-EM Imaging. Surface Structure at the Atomic Level, Y. Kratish, T. Nakamuro, Y. Liu, J. Li, I. Tomotsuka, K. Harano, E. Nakamura, T. Marks, Bull. Chem. Soc. Jpn., 94, 427–432 (2021). (BCSJ Award Article, Selected as Cover Picture, open-access)
48. SHROOM3, The Gene Associated with Renal Functional Decline, Affects The Podocyte Structure, R. Matsuura, A. Hiraishi, L. Holzman, H. Hanayama, K. Harano, E. Nakamura, Y. Hamasaki, K. Doi, M. Nangaku, E. Noiri, Sci. Rep. 10, 21103 (2020).
47. Aryl Radical Addition to Curvatures of Carbon Nanohorns for Single-Molecule-Level Molecular Imaging, K. Kamei, T. Shimizu, K. Harano, E. Nakamura, Bull. Chem. Soc. Jpn., 93, 1603-1608 (2020).
46. Ultra-fast Electron Microscopic Imaging of Single Molecules with Direct Electron Detection Camera and Noise Reduction, J. Stuckner, T. Shimizu, K. Harano, E. Nakamura, M. Murayama, Microsc. Microanal., 26, 667–675 (2020).
45. Real-time Video Imaging of Mechanical Motions of a Single Molecular Shuttle with Sub-millisecond Sub-angstrom Precision, T. Shimizu, D. Lungerich, J. Stuckner, M. Murayama, K. Harano, E. Nakamura, Bull. Chem. Soc. Jpn., 93, 1079-1085 (2020). (BCSJ Award Article, Open Access, Selected as Cover Picture)
44. Spiro-conjugated Carbon/Heteroatom-bridged p-Phenylenevinylenes: Synthesis, Properties, and Microcrystal Electron Crystallographic Analysis of Racemic Solid Solutions, H. Hamada, T. Nakamuro, K. Yamashita, H. Yanagisawa, O. Nureki, M. Kikkawa, K. Harano, R. Shang, E. Nakamura, Bull. Chem. Soc. Jpn., 93, 776–782 (2020). (BCSJ Award Article, Open Access, Selected as Cover Picture)
43. Cyclodextrins as Surfactants for Solubilization and Purification of Carbon Nanohorn Aggregates, H. Hanayama, J. Yamada, K. Harano, E. Nakamura, Chem. Asian J., 15, 1549–1552 (2020).
42. Bifurcation of Self-Assembly Pathways to Sheet or Cage Controlled by Kinetic Template Effect, L. H. Foianesi-Takeshige, S. Takahashi, T. Tateishi, R. Sekine, A. Okazawa, W. Zhu, T. Kojima, K. Harano, E. Nakamura, H. Sato, S. Hiraoka, Commun. Chem., 2, 128 (2019).
41. Atomistic Structures and Dynamics of Prenucleation Clusters in MOF-2 and MOF-5 Syntheses, J. Xing, L. Schweighauser, S. Okada, K. Harano, E. Nakamura, Nat. Commun., 10, 3608 (2019).
40. Preparation of Hierarchically Assembled Silver Nanostructures based on the Morphology of Crystalline Peptide‐Silver(I) Complexes, R. Miyake, Y. Nitanai, Y. Nakagawa, J. Xing, K. Harano, E. Nakamura, J. Okabayashi, T. Minamikawa, K. Uruma, K. Kanaizuka, M. Kurihara, ChemPlusChem, 84, 295–301 (2019). (Highlighted in ChemistryViews)
39. Pyrazine-Incorporated Graphdiyne Nanofilm as a Metal-Free Electrocatalyst for Hydrogen Evolution Reaction, R. Sakamoto, R. Shiotsuki, K. Wada, N. Fukui, H. Maeda, J. Komeda, R. Sekine, K. Harano, H. Nishihara, J. Mater. Chem. A., 6, 22189-22194 (2018).
38. Neutron Scattering Reveals Water Confined in a Watertight Bilayer Vesicle, W. Abuillan, A. S. Becker, B. Demé, T. Homma, H. Isobe, K. Harano, E. Nakamura, M. Tanaka, J. Am. Chem. Soc., 140, 11261-11266 (2018).
37. Hierarchical Assembly of siRNA with Tetraamino Fullerene in Physiological Conditions for Efficient Internalization into Cells and Knockdown, K. Minami, K. Okamoto, K. Harano, E. Noiri, E. Nakamura, ACS Appl. Mater. Interfaces, 10, 19347-19534 (2018).
36. Flexibility of Components Alters the Self-assembly Pathway of Pd2L4 Coordination Cages, S. Kai, S. P. Maddala, T. Kojima, S. Akagi, K. Harano, E. Nakamura, S. Hiraoka, Dalton Trans., 47, 3258-3263 (2018). (Selected as Front cover)
35. Acid-Responsive Conductive Nanofiber of Tetrabenzoporphyrin Made by Solution Processing, Y. Zhen, K. Inoue, Z. Wang, T. Kusamoto, K. Nakabayashi, S. Ohkoshi, W. Hu, Y. Guo, K. Harano, E. Nakamura, J. Am. Chem. Soc., 140, 62-65 (2018). (Selected as Cover picture)
34. Direct Microscopic Analysis of Individual C60 Dimerization Events: Kinetics and Mechanisms, S. Okada, S. Kowashi, L. Schweighauser, K. Yamanouchi, K. Harano, E. Nakamura, J. Am. Chem. Soc., 139, 18281-18287 (2017).
33. Bis(dipyrrinato)zinc(II) Complex Chiroptical Wires: Exfoliation into Single Strands and Intensification of Circularly Polarized Luminescence, R. Aoki, R. Toyoda, J. F. Kögel, R. Sakamoto, J. Kumar, Y. Kitagawa, K. Harano, T. Kawai, H. Nishihara, J. Am. Chem. Soc., 139, 16024-16027 (2017).
32. Experimental Study on Interconversion between Cubic MOF-5 and Square MOF-2 Arrays, L. Schweighauser, K. Harano, E. Nakamura, Inorg. Chem. Commun., 84, 1-4 (2017).
31. Conical Ionic Amphiphiles Endowed with Micellization Ability but Lacking Air- and Oil-Water Interfacial Activity, H. Nitta, K. Harano, M. Isomura, E. H. G. Backus, M. Bonn, E. Nakamura, J. Am. Chem. Soc., 139, 7677-7680 (2017).
30. Heterogeneous Catalase-like Activity of Gold(I)-Cobalt(III) Metallosupramolecular Ionic Crystals, M. Yamada, N. Yoshinari, N. Kuwamura, T. Saito, S. Okada, S. P. Maddala, K. Harano, E. Nakamura, K. Yamagami, K. Yamanaka, A. Sekiyama, T. Suenobu, Y. Yamada, T. Konno, Chem. Sci., 8, 2671-2676 (2017).
29. Supramolecular Differentiation for Constructing Anisotropic Fullerene Nanostructures by Time-Programmed Control of Interfacial Growth, P. Bairi, K. Minami, J. P. Hill, W. Nakanishi, L. K. Shrestha, C. Liu, K. Harano, E. Nakamura, K. Ariga, ACS Nano, 10, 8796-8802 (2016).
28. Nanoscale Control of Polymer Assembly on a Synthetic Catalyst-Bilayer System, R. M. Gorgoll, K. Harano, E. Nakamura, J. Am. Chem. Soc., 138, 9675-9681 (2016).
27. Chemical Pathways Connecting Lead(II) Iodide and Perovskite via Polymeric Plumbate(II) Fiber, Y. Guo, K. Shoyama, W. Sato, Y. Matsuo, K. Inoue, K. Harano, C. Liu, H. Tanaka, E. Nakamura, J. Am. Chem. Soc., 137, 15907-15914 (2015).
26. Cooperative Self-Assembly of Gold Nanoparticles on the Hydrophobic Surface of Vesicles in Water, R. M. Gorgoll, T. Tsubota, K. Harano, E. Nakamura, J. Am. Chem. Soc., 137, 7568-7571 (2015).
25. Electron Microscopic Observation of Selective Excitation of Conformational Change of a Single Organic Molecule, R. M. Gorgoll, E. Yücelen, A. Kumamoto, N. Shibata, K. Harano, E. Nakamura, J. Am. Chem. Soc., 137, 3474-3477 (2015).
24. Organic Solid Solution Composed of Two Structurally Similar Porphyrins for Organic Solar Cells, Y. Zhen, H. Tanaka, K. Harano, S. Okada, Y. Matsuo, E. Nakamura, J. Am. Chem. Soc., 137, 2247-2252 (2015).
23. DNA Binding of Pentaamino[60]fullerene Synthesized using Click Chemistry, H. Niita, K. Minami, K. Harano, E. Nakamura, Chem. Lett., 44, 378-380 (2015). (Selected as Editor's Choice, open-access article)
22. High-Density Display of Protein Ligands on Self-Assembled Capsules via Noncovalent Fluorous Interactions, K. Harano, J. Yamada, S. Mizuno, E. Nakamura, Chem. Asian J., 10, 172-176 (2015).
21. Fabrication of NIR-Excitable SERS-Active Composite Particles Comprised of Densely-Packed Au Nanoparticles on Polymer Microparticles, M. Kanahara, H. Satoh, T. Higuchi, A. Takahara, H. Jinnai, K. Harano, S. Okada, E. Nakamura, Y. Matsuo, H. Yabu, Part. Part. Syst. Charact., 32, 441-447 (2015). (Selected as Cover Picture)
20. Enhancement in the Efficiency of an Organic-Inorganic Hybrid Solar Cell with a Doped P3HT Hole-Transporting Layer on a Void-Free Perovskite Active Layer, Y. Guo, C. Liu, K. Inoue, K. Harano, H. Tanaka, E. Nakamura, J. Mater. Chem. A, 2, 13827-13830 (2014).
19. siRNA Delivery Targeting to the Lung via Agglutination-Induced Accumulation and Clearance of Cationic Tetraamino Fullerene, K. Minami, K. Okamoto, K. Doi, K. Harano, E. Noiri, E. Nakamura, Sci. Rep., 4, 4916 (2014).
18. Formation of a Polycrystalline Film of Donor Material on PEDOT:PSS Buffer Induced by Crystal Nucleation, K. Harano, S. Okada, S. Furukawa, H. Tanaka, E. Nakamura, J. Polym. Sci. Part B: Polym. Phys., 52, 833-841 (2014).
17. Photo-cross-linking of Exterior of Fullerene Bilayer that Prevents Vesicle Aggregation, K. Harano, A. Narita, E. Nakamura, Chem. Lett., 43, 877-879 (2014). (Selected as Editor's Choice and Cover Picture, open-access article)
16. Conformational Analysis of Single Perfluoroalkyl Chains by Single-Molecule Real-Time Transmission Electron Microscopic Imaging, K. Harano, S. Takenaga, S. Okada, Y. Niimi, N. Yoshikai, H. Isobe, K. Suenaga, H. Kataura, M. Koshino, E. Nakamura, J. Am. Chem. Soc., 136, 466-473 (2014).
15. Binding of Aromatic Molecules in the Fullerene-Rich Interior of a Fullerene Bilayer Vesicle in Water, K. Harano, R. M. Gorgoll, E. Nakamura, Chem. Commun., 49, 7629-7631 (2013).
14. Photocrosslinking of Fullerene Vesicles that Prevents Phase Transition and Decreases Water Permeation, K. Harano, A. Narita, E. Nakamura, Chem. Lett., 42, 1176-1178 (2013). (Selected as Editor's Choice, open-access article)
13. Polymer Janus Particles Containing Block-Copolymer Stabilized Magnetic Nanoparticles, H. Yabu, M. Kanahara, M. Shimomura, T. Arita, K. Harano, E. Nakamura, T. Higuchi, H. Jinnai, ACS Appl. Mater. Interfaces, 5, 3262-3266 (2013).
12. Protein-Coated Nanocapsules via Multilevel Surface Modification. Controlled Preparation and Microscopic Analysis at Nanometer Resolution, K. Harano, K. Minami, E. Noiri, K. Okamoto, E. Nakamura, Chem. Commun., 49, 3525-3527 (2013).
11. Heterogeneous Nucleation of Organic Crystals Mediated by Single-Molecule Templates, K. Harano, T. Homma, Y. Niimi, M. Koshino, K. Suenaga, L. Leibler, E. Nakamura, Nat. Mater., 11, 877-881 (2012). (Highlighted in News and Views, Nat. Mater., 11, 838-840 (2012).)
10. Preparation and Properties of Vesicles Made of Nonpolar/Polar/Nonpolar Fullerene Amphiphiles, T. Homma, K. Harano, H. Isobe, E. Nakamura, J. Am. Chem. Soc., 133, 6364-6370 (2011).
9. Nanometer-Sized Fluorous Fullerene Vesicles in Water and on Solid Surfaces, T. Homma, K. Harano, H. Isobe, E. Nakamura, Angew. Chem. Int. Ed., 49, 1665-1668 (2010).
8. Induced-Fit Formation of a Tetrameric Organic Capsule Consisting of Hexagram-Shaped Amphiphile Molecules, S. Hiraoka, K. Harano, T. Nakamura, M. Shiro, M. Shionoya, Angew. Chem., Int. Ed., 48, 7006-7009 (2009).
7. A Self-Assembled Organic Capsule Formed from the Union of Six Hexagram-Shaped Amphiphile Molecules, S. Hiraoka, K. Harano, M. Shiro, M. Shionoya, J. Am. Chem. Soc., 130, 14368-14369 (2008).
6. Mono- and Penta-Addition of Enol Silyl Ethers to [60]Fullerene, E. Nakamura, S. Mouri, Y. Nakamura, K. Harano, and H. Isobe, Org. Lett., 10, 4923-4926 (2008).
5. Imaging of Conformational Change of Biotinylated Triamide Molecules Covalently Bonded to Carbon Nanotube Surface, E. Nakamura, M. Koshino, T. Tanaka, Y. Niimi, K. Harano, Y. Nakamura, and H. Isobe, J. Am. Chem. Soc., 130, 7808-7809 (2008).
4. 3 nm-Scale Molecular Switching between Fluorescent Coordination Capsule and Nonfluorescent Cage, K. Harano, S. Hiraoka, M. Shionoya, J. Am. Chem. Soc., 129, 5300-5301. (2007)
3. Isostructural Coordination Capsules for a Series of Ten Different d5-d10 Transition-Metal Ions, S. Hiraoka, K. Harano, M. Shiro, Y. Ozawa, N. Yasuda, K. Toriumi, M. Shionoya, Angew. Chem., Int. Ed., 45, 6488-6491 (2006). (selected as VIP and Cover Picture)
2. Quantitative Dynamic Interconversion between AgI-Mediated Capsule and Cage Complexes Accompanying Guest Encapsulation/Release, S. Hiraoka, K. Harano, M. Shiro, M. Shionoya, Angew. Chem., Int. Ed., 44, 2727-2731 (2005).
1. Quantitative Formation of Sandwich-Shaped Trinuclear Silver(I) Complexes and Dynamic Feature of Their P↔M Flip Motion in Solution, S. Hiraoka, K. Harano, T. Tanaka, M. Shiro, M. Shionoya, Angew. Chem., Int. Ed., 42, 5182-5185 (2003).
Review/Account:
7. Structures, Fundamental Properties, and Potential Applications of Low-Dimensional C60 Polymers and Other Nanocarbons: A Review, J. Onoe, Y.Noda, Q. Wang, K. Harano, M. Nakaya, T. Nakayama, Sci. Tech. Adv. Mater., 25, 2346068 (2024).
6. Cinematographic Study of Stochastic Chemical Events at Atomic Resolution, K. Harano, T. Nakamuro, E. Nakamura, Microscopy, 73, 101-116 (2024).
5. 分子映像によって開拓する動的分子科学の新しい世界,原野幸治,中室貴幸,中村栄一,顕微鏡, 57, 59−64 (2022).
4. Self-Assembly Mechanism in Nucleation Processes of Molecular Crystalline Materials, K. Harano, Bull. Chem. Soc. Jpn., 94, 462−473 (2021). (Open-access)
3. Interfacial Chemistry of Conical Fullerene Amphiphiles in Water, K. Harano, E. Nakamura, Acc. Chem. Res., 52, 2090−2100 (2019).
2. Chemical Kinetics Study through Observation of Individual Reaction Events with Atomic-Resolution Electron Microscopy, E. Nakamura, K. Harano, Proc. Jpn. Acad., Ser. B, 94, 428−440 (2018). (Selected as Cover)
1. 結晶はどのようにしてできるか,原野幸治,化学と教育, 63, 384-387 (2015).
著書 :
2. Koji Harano, Eiichi Nakamura, Conformational Analysis of Organic Molecules with Single-Molecule Atomic-Resolution Real-Time Transmission Electron Microscopy (SMART-TEM) Imaging. In Molecular Technology, Volume 4: Synthesis Innovation, Eds: H. Yamamoto, T. Kato, pp 339-368, Wiley-VCH, (2019).
1. π電子研究の歴史と将来展望(分担執筆),原野幸治,中村栄一,未来材料を創出するπ電子系の化学(CSJカレントレビュー12),化学同人,20-24 (2013).
記事・解説 :
13. 分子映像によって開拓する動的分子科学の新しい世界, 原野幸治, 中室貴幸, 中村栄一, 顕微鏡, 57(2), 59–64 (2022).
12. 原子番号相関(ZC)分子模型の提案–新時代の化学教育・研究のための分子描画パラメータ, 原野幸治, 中村栄一, 化学, 77(8), 36–40 (2022).
11. 高速・高分解能透過電子顕微鏡で開拓する原子・分子・分子集合体の化学, 原野幸治, 中室貴幸, 中村栄一, NEW DIAMOND, 38(2), 12–16 (2022).
10. 映像分子科学の現場から, 原野幸治, 化学と工業, 74, 875 (2021).
9. シクロデキストリンの非包接型ゲスト認識, 原野幸治, 化学と工業, 74, 513 (2021).
8. 世界最高速の動画撮影でひもとく分子の世界-カメラは見た!分子が動く決定的瞬間-,清水俊樹, 原野幸治,中村栄一,化学, 75(11), 12-16 (2020).
7. 単分子原子分解能実時間電子顕微鏡法による化学反応研究, 原野幸治, 中村栄一, 化学と工業, 73, 16-18 (2020).
6. アスファルテン分子の可視化,原野幸治,日本エネルギー学会機関誌えねるみくす, 98, 676-682 (2019).
5. 目に見えない微結晶の構造を解析する! -マイクロ電子回折で三次元分子構造を決定,原野幸治,劉 東欣,中室貴幸,中村栄一,化学, 74(5), 49-53 (2019).
4. 化学反応を顕微鏡で追跡する時代が到来,岡田 賢,山内 薫,原野幸治,中村栄一,現代化学, 566, 27-31 (2018).
3. 原子分解能顕微鏡で化学反応機構を調べる!-一体いくつの分子を調べればよいのだろうか-,岡田 賢,山内 薫,原野幸治,中村栄一,化学, 73(4), 12-16 (2018).
2. お茶のなかの分子世界,原野幸治,現代化学, 556, 384-387 (2017).
1. 外部刺激に応答して伸縮する配位高分子錯体,原野幸治,化学と工業, 58, 593 (2005).