樋口昌芳－論文

論文

h-Index 42
[The most cited paper of the year]: 当該年の最多被引用論文
[One of the most cited papers]: 被引用回数上位40報 (被引用回数39回以上)
2025年の論文／著書／雑誌／その他: Construction of Heterometallic Coordination Nanosheets Comprising Both Inert and Labile Metal Ions Together via Metalloligand Approach
M. K. Bera, S. Sarmah, A. Maity, M. Higuchi, Inorg. Chem. (2025) ASAP. (Open Access)
10.1021/acs.inorgchem.5c00224
Published online: 3 April 2025
Published in issue:
2024年の論文／著書／雑誌／その他: Triple-Band Electrochromic Switching among Visible (400–750 nm), NearIR-I (750–1000 nm), and NearIR-II (1000–1600 nm) Regions with Triple-Redox-Active Metallosupramolecular Polymers
D. C. Santra, S. Mondal, B. Prusti, M. Higuchi
ACS Appl. Opt. Mater., 2(6), 1117–1127 (2024).
10.1021/acsaom.4c00108
Published online: 21 May 2024
Published in issue: 28 June 2024

Microwave-Assisted Quick Synthesis of Ru(II)-Based Metallosupramolecular Polymer for Improved Electrochromic Properties
U. Rana, D. C. Santra, B. Prusti, C. Chakraborty, T. Ikeda, Y. Saito, K. Takeuchi, R. Nagahata, M. Higuchi
Macromol. Chem. Phys., 225(5), 2300381 (2024). (Selected to cover)
10.1002/macp.202300381
Published online: 8 January 2024
Published in issue: March 2024

In Situ Film Growth of Metallosupramolecular Polymer via Electropolymerization and Its Application as Electrochromic Film
C-W. Hu, S. Jena, T. Sato, J. Zhang, S. Moriyama, M. Higuchi
ACS Appl. Polym. Mater., 6(1), 441-447 (2024). (Selected to supplementary cover)
10.1021/acsapm.3c01937
Published online: 18 December 2023
Published in issue: 12 January 2024

Heterometallic Supramolecular Polymers: from Synthesis to Properties and Applications
M. K. Bera, S. Sarmah, D. C. Santra, M. Higuchi
Coord. Chem. Rev., 501, 215573 (2024).
10.1016/j.ccr.2023.215573

M. Higuchi,
Electrochromic Metallo-Supramolecular Polymers, NIMS Monograph Series (Springer 2024) under revision.

Electrochromic Polymer
M. Higuchi
Encyclopedia of Polymers, Polymeric Materials, and Polymer Technology (Taylor & Francis/Routledge 2023) in press.

Chapter 12, Metallosupramolecular polymers as display materials
M. Higuchi
Functional Macromolecular Complexes (Royal Society of Chemistry 2024) in press.

エレクトロクロミック材料による画像革命
樋口昌芳
高分子 (高分子学会、2024) Vol. 73, 9月号 453-455.

電気で色が変わる窓の超低消費電力駆動の「材料」とその可能性
樋口昌芳
月刊MATERIAL STAGE (技術情報協会、2024) Vol. 24, 7月号 63-65.
2023年の論文／著書／雑誌／その他: Highly Durable Electrochromic Devices for More than 100,000 Cycles with Fe(II)-Based Metallo-Supramolecular Polymer by Optimization of the Device Conditions
S. Mondal, S. Roy, Y. Fujii, M. Higuchi
ACS Appl. Electron. Mater., 5(12), 6677–6685 (2023). (Selected to supplementary cover)
10.1021/acsaelm.3c01143
Published online: 5 December 2023
Published in issue: 26 December 2023

Electrochromic Ru-Based Metallo-Supramolecular Polymer with Layered Inorganic-Organic Hybrid Nanocomposite for Improved Electrochemical Properties
K. Fujii, D. C. Santra, M. K. Bera, T. Wakahara, R. Nagahata, M. Higuchi
ACS Appl. Polym. Mater., 5(11), 8808-8821 (2023). (Selected to supplementary cover)
10.1021/acsapm.3c00837
Published online: 19 October 2023
Published in issue: 10 November 2023

Reversible Electrochromic/Electrofluorochromic Dual Switching in Zn(II)-Based Metallo-Supramolecular Polymer Film
S. Mondal, D. C. Santra, S. Roy, Y. S. L. V. Narayana, T. Yoshida, Y. Ninomiya, M. Higuchi
ACS Appl. Mater. Interfaces, 15(36), 42912–42919 (2023).
10.1021/acsami.3c06673
Published online: 30 August 2023
Published in issue: 13 September 2023

Flexible Multicolor Rewritable Paper Coated with Metallo-supramolecular Polymers for Electrochromic Printing and Natural Erasing by Humidity
J. Zhang, S. R. Jena, M. Higuchi
ACS Appl. Polym. Mater., 5(9), 6950–6957 (2023). (Selected to supplementary cover)
10.1021/acsapm.3c00991
Published online: 23 August 2023
Published in issue: 8 September 2023

2.1 メタロ超分子ポリマーを用いたエレクトロクロミック調光デバイスの開発
樋口昌芳
スマートウィンドウ(調光窓)の開発動向 (CMC出版、2023年10月刊行) 15-20.
ISBN: 978-4-7813-1746-5

Recent Progress on Metallo-Supramoleculear Polymers and the Electrochromic Devices Fabrication
Masayoshi Higuchi
有機合成化学協会誌 (有機合成化学協会、2023) Vol. 81, 11月号 1089-1095. Open Acess
Journal of Synthetic Organic Chemistry, Japan, 81(11), 1089-1095 (2023). Open Access

層状無機－有機共有結合体／メタロ超分子ポリマー複合体のエレクトロクロミック特性
藤井和子、樋口昌芳
セラミックス (日本セラミックス協会、2023) Vol. 58, 6月号 369-372.
2022年の論文／著書／雑誌／その他: Electrochromic Coordination Polymers,
M. Higuchi,
Bull. Jpn. Soc. Coord. Chem., 79, 68-77 (2022). (Award Account, Open Access)
10.4019/bjscc.79.68
Publication Date: June 6, 2022

Rational Synthesis of Ruthenium-Based Metallo-Supramolecular Polymers as Heterogeneous Catalysts for Catalytic Transfer Hydrogenation of Carbonyl Compounds,
Z.-J, Gong, Y. S. L. V. Narayana, Y.-C. Lin, W.-H. Huang, W.-N. Su, Y.-P. Li, M. Higuchi, W.-Y. Yu,
Appl. Catal. B, 312, 121383(1-12) (2022).
10.1016/j.apcatb.2022.121383
Published online: April 8, 2022
[The most cited paper of the year]

Nanocomposites of Fe(II)-Based Metallo-Supramolecular Polymer and a Layered Inorganic–Organic Hybrid for Improved Electrochromic Materials,
K. Fujii, M. K. Bera, D. C. Santra, M. Higuchi,
Polymers (Special Issue "Applications of Polymers in Energy and Environmental Sciences"), 14(5), 915(1-16) (2022). (Open Access)
10.3390/polym14050915
Published online: February 25, 2022

2-63　透明ディスプレイ
樋口昌芳
高分子材料の事典　高分子学会編集 (朝倉書店、2022年10月刊行) 266-267.
ISBN:978-4-254-25272-9

2-64　電子ペーパー
樋口昌芳
高分子材料の事典　高分子学会編集 (朝倉書店、2022年10月刊行) 268-269.
ISBN:978-4-254-25272-9

電気で色が変わる窓の超低消費電力駆動と普及に向けて
樋口昌芳
月刊クリーンエネルギー (日本工業出版、2022) Vol. 31, 9月号 26-30.

グラデーション変化する調光ガラスの開発とその可能性
樋口昌芳
月刊機能材料 (シーエムシー出版、2022) Vol. 42, 2月号 12-18.

未来創造発明賞を受賞して
樋口昌芳
月報はつめい (発明協会、2022) 8月号, 2.

メタロ超分子ポリマーを用いたエレクトロクロミック調光デバイスの開発
樋口昌芳
つくばサイエンス・アカデミー会誌 (つくばサイエンス・アカデミー、2022) Vol. 40, 7月号 5.

国際連携についての私的な演繹的考察
樋口昌芳
高分子 (高分子学会、2022) Vol. 71, 3月号 109.
2021年の論文／著書／雑誌／その他: Ru(II)-Based Metallo-Supramolecular Polymer with Tetrakis(N-methylbenzimidazolyl)bipyridine for a Durable, Nonvolatile, and Electrochromic Device Driven at 0.6 V,
D. C. Santra, S. Mondal, T. Yoshida, Y. Ninomiya, M. Higuchi,
ACS Appl. Mater. Interfaces, 13(26), 31153–31162 (2021).
10.1021/acsami.1c07275

Designed, Flexible Electrochromic Display Device with Fe(II)-Based Metallo-Supramolecular Polymer Using Mechanically Etched ITO Film,
M. Higuchi, Y. Fujii,
J. Photopolym. Sci. Technol., 34(2), 175–180 (2021). (Open Access)
10.2494/photopolymer.34.175

Designed Electrochromic Display Devices with Ru(II)-Based Metallo-Supramolecular Polymer For Experience-Based Exhibits at Ehime Prefectural Science Museum,
M. Higuchi, Y. Fujii, Y. Hisamatsu,
ITE Trans. Media Technol. Appl., 9(4), 228-233 (2021). (Open Access)
10.3169/mta.9.228

Durable Electrochromic Devices Driven at 0.8 V by Complementary Chromic Combination of Metallo-Supramolecular Polymer and Prussian Blue Analogues for Smart Windows with Low-Energy Consumption,
H.-C. Lu, L.-Y. Hsiao, S.-Y. Kao, Y. Seino, D. C. Santra, K.-C. Ho, M. Higuchi,
ACS Appl. Electron. Mater., 3(5), 2123–2135 (2021).
10.1021/acsaelm.1c00132
[The most cited papers of the year]

One-Step Synthesis of Three-Dimensionally Hyperbranched Fe(II)-Based Metallo-Supramolecular Polymer Using Asymmetrical Ditopic Ligand for Durable Electrochromic Films with Wide Absorption, Large Optical Contrast, and High Coloration Efficiency,
Y. S. L. V. Narayana, S. Mondal, U. Rana, Y. Ninomiya, D. C. Santra, T. Yoshida, M. Higuchi,
ACS Appl. Electron. Mater., 3(5), 2044–2055 (2021).
10.1021/acsaelm.1c00061

Stepwise Introduction of Three Different Transition Metals in Metallo-Supramolecular Polymer for Quad-Color Electrochromism,
M. K. Bera, Y. Ninomiya, M. Higuchi,
Commun. Chem., 4, 56(1-12) (2021). (Open Access)
10.1038/s42004-021-00495-1
Published on May 3, 2021.
[The most cited papers of the year]

6章11節メタロ超分子ポリマーの開発とスマートウインドウへの応用
樋口昌芳
建築・住宅用高分子の要求性能とその開発、性能評価 (技術情報協会、2021) 279-284.
出版日：2021年4月30日

Part II　6章　メタロ超分子ポリマーのエレクトロクロミック特性と表示デバイス応用
樋口昌芳
未来を拓く多彩な色素材料　CSJカレントレビュー第40号 (化学同人、2021) 77-81.
出版日：2021年3月10日

錯体のエレクトロクロミズム
樋口昌芳
化学と工業 (日本化学会、2021) Vol. 74, 11月号 841.

設立目的におけるパラドックス　－それでも新領域創成を目指すわけ
樋口昌芳
化学と工業 (日本化学会、2021) Vol. 74, 11月号 832-835.

調光ガラスが世界の窓を変える　－エレクトロクロミック材料開発の最前線
樋口昌芳
化学 (2021年の化学：最新のトピックス) (化学同人、2021) Vol. 76, 10月号 74-75.
2020年の論文／著書／雑誌／その他: Dual-Redox System of Metallo-supramolecular Polymers for Visible-to-Near-IR Modulable Electrochromism and Durable Device Fabrication,
S. Mondal, D. C. Santra, Y. Ninomiya, T. Yoshida, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(52), 58277–58286 (2020). (Selected to supplementary cover)
10.1021/acsami.0c18109

Synthesis of Alternated Heterobimetallic Supramolecular Polymer Based on Ru(II) and Fe(II),
M. K. Bera, Y. Ninomiya, M. Higuchi,
Molecules (Special Issue "Coordination Programming for Electro-, Magneto-, and Photofunctional Molecular Systems: A Theme Issue in Honor of Prof. Dr. Hiroshi Nishihara"), 25(22), 5261(1-9) (2020). (Open access)
10.3390/molecules25225261

Durable Supercapattery Film with Dual-Branched Dense Hexagonal Fe(II)-Based Coordination Nanosheets for Flexible Power Sources,
S. Mondal, Y. Ninomiya, M. Higuchi,
ACS Appl. Energy Mater., 3(11), 10653–10659 (2020).
10.1021/acsaem.0c01720

Green-to-Black Electrochromic Copper(I)-Based Metallo-Supramolecular Polymer with a Perpendicularly Twisted Structure,
M. D. Hossain, C. Chakraborty, U. Rana, S. Mondal, H.-J. Holdt, M. Higuchi,
ACS Appl. Polym. Mater., 2(11), 4449-4454 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00559

Luminescent Amphiphilic Nanogels by Terpyridine-Zn(II) Ion Complexation of Polymeric Micelles,
D. A. Saleh, U. Rana, M. Higuchi, A. Sosnik,
Mater. Today Chem., 18, 100359(1-13) (2020).
10.1016/j.mtchem.2020.100359

Helical Fe(II)-Based Metallo-Supramolecular Polymers: Effect of Crown Ether Groups Located outside the Helix on Hydrous Proton Channel Formation,
C. Chakraborty, U. Rana, Y. S L V Narayana, S. Moriyama, M. Higuchi,
ACS Appl. Polym. Mater., 2(11), 4521-4530 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00611

One-Pot Synthesis of Three-Dimensionally Hyperbranched Eu/Fe-Based Heterometallo-Supramolecular Polymers as Thermally Tough Proton-Conducting Nanoparticles,
Y. S L V Narayana, U. Rana, C. Chakraborty, T. Yoshida, M. Higuchi,
ACS Appl. Polym. Mater., 2(11), 4439-4448 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00541

Multifunctional Pt(II)-Based Metallo-Supramolecular Polymer with Carboxylic Acid Groups: Electrochemical, Mechanochemical, Humidity, and pH Response,
C. Chakraborty, U. Rana, S. Moriyama, M. Higuchi,
ACS Appl. Polym. Mater., 2(9), 4149-4159 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00782

Flexible Rewritable Electrochromic Device with Handwriting Feature,
S.-Y. Peng, C.-H. Su, M. Higuchi, K.-C. Ho, Y.-C. Liao,
Sol. Energy Mater. Sol. Cells, 217, 110738(1-8) (2020).
10.1016/j.solmat.2020.110738

Dual-Branched Dense Hexagonal Fe(II)-Based Coordination Nanosheets with Red-to-Colorless Electrochromism and Durable Device Fabrication,
S. Mondal, Y. Ninomiya, T. Yoshida, T. Mori, M. K. Bera, K. Ariga, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(28), 31896-31903 (2020).
10.1021/acsami.0c05921

Electrochromic Os-Based Metallo-Supramolecular Polymer: Electronic State Tracking by in situ XAFS, IR, and Impedance Spectroscopies,
T. Yoshida, M. K. Bera, Y. S L V Narayana, S. Mondal, H. Abe, M. Higuchi,
RSC Adv., 10(41), 24691-24696 (2020). (Open access)
10.1039/D0RA03236K

Ni(II)-Based Metallosupramolecular Polymer with Carboxylic Acid Groups: A Stable Platform for Smooth Imidazole Loading and the Anhydrous Proton Channel Formation,
Y. S L V Narayana, T. Yoshida, M. K. Bera, S. Mondal, M. Higuchi,
ACS Omega, 5(24), 14796-14804 (2020). (Selected to supplementary cover, Open access)
10.1021/acsomega.0c01735

Electrochromic Fe(II)-Based Metallo-Supramolecular Polymers: Color Modulation by Spacer Modification in Bisterpyridine Ligand,
Y. Ninomiya, T. Yoshida, M. Higuchi,
Chem. Lett., 49(9), 1003-1005 (2020).
10.1246/cl.200307

Thermally Tough Electrochromic Devices with Metallo-Supramolecular Polymer: Investigation of Gel Electrolyte Component and Fabrication Process,
M. Kanao, Y. Seino, M. Higuchi,
J. Photopolym. Sci. Technol., 33(4), 405-412 (2020).
10.2494/photopolymer.33.405

Transparent Supercapacitor Display with Redox-Active Metallo-Supramolecular Polymer Films,
S. Mondal, T. Yoshida, S. Maji, K. Ariga, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(14), 16342-16349 (2020).
10.1021/acsami.9b23123

Molecular Level Assembly for High-Performance Flexible Electrochromic Energy Storage Devices,
G. Cai, J. Chen, J. Xiong, A. L.-S. Eh, J. Wang, M. Higuchi, P. S. Lee,
ACS Energy Lett., 5(4), 1159-1166 (2020).
10.1021/acsenergylett.0c00245
[The most cited paper of the year]
[One of the most cited papers]

Constructing Alternated Heterobimetallic [Fe(II)/Os(II)] Supramolecular Polymers with Diverse Solubility for Facile Fabrication of Voltage-Tunable Multicolor Electrochromic Devices,
M. K. Bera, Y. Ninomiya, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(12), 14376-14385 (2020).
10.1021/acsami.9b21966

Reversible Four-Color Electrochromism Triggered by the Electrochemical Multi-Step Redox of Cr-Based Metallo-Supramolecular Polymers,
T. Yoshida, Y. Ninomiya, M. Higuchi,
RSC Adv., 10(18), 10904-10909 (2020). (Open access)
10.1039/d0ra00676a

Proton Conductivity of Metallo-Supramolecular Polymer Boosted by Lithium Ions,
Y. S L V Narayana, T. Yoshida, C. Chakraborty, M. K. Bera, M. Higuchi,
ACS Appl. Polym. Mater., 2(2), 326-334 (2020). (Selected to supplementary cover)
10.1021/acsapm.9b00818

Precise Synthesis of Alternate Fe(II)/Os(II)-Based Bimetallic Metallo-Supramolecular Polymer,
M. K. Bera, Y. Ninomiya, T. Yoshida, M. Higuchi,
Macromol. Rapid Commun. (Special Issue: 100 Years of Macromolecular Chemistry), 41(1), 1900384(1-4) (2020). (Selected to back cover, Free access)
10.1002/marc.201900384

Electrolyte Gated-Organic Field Effect Transistors Functionalized by Lipid Monolayers with Tunable pH Sensitivity for Sensor Applications,
T. P. Nguy, R. Hayakawa, V. Kilinc, M. Petit, Y. S L V Narayana, M. Higuchi, J.-M. Raimundo, A. Charrier, Y. Wakayama,
Appl. Phys. Express, 13, 011005(1-5) (2020).
10.7567/1882-0786/ab5322

4.1 高分子錯体を利用した表示材料
樋口昌芳
フロンティア機能高分子金属錯体　錯体化学会フロンティア選書 (三共出版、2020) 343-359.

電気で色が変わるガラス
樋口昌芳
化学と教育 (日本化学会、2020) Vol. 68, 12月号 524-527.

エレクトロクロミック調光ガラス用ポリマー材料
樋口昌芳
光アライアンス (日本工業出版、2020) Vol. 31, 11月号 47-50.

メタロ超分子ポリマーを用いたエレクトロクロミックデバイス
樋口昌芳
科学と工業 (大阪工研協会、2020) Vol. 94, 7月号 175-181.

遮光と眺望を両立する窓～エレクトロクロミック調光ガラス
樋口昌芳
プラスチック (日本工業出版、2020) Vol. 71, 5月号 37-40.

エレクトロクロミックデバイス用ポリマー材料
樋口昌芳
光技術コンタクト (日本オプトメカトロニクス協会、2020) Vol. 58, 2月号 24-29.
2019年の論文／著書: Construction of Coordination Nanosheets Based on Tris(2,2'-Bipyridine)-Iron (Fe2+) Complexes as Potential Electrochromic Materials,
M. K. Bera, T. Mori, T. Yoshida, K. Ariga, M. Higuchi,
ACS Appl. Mater. Interfaces, 11(12), 11893-11903 (2019). (Selected to supplementary cover)
10.1021/acsami.8b22568
[The most cited paper of the year]
[One of the most cited papers]

Efficient White-Light-Emission from a Heterometallo-Supramolecular Polymer with Eu(III) and Zn(II) Ions Introduced Alternately,
T. Sato, M. Higuchi,
Tetrahedron Lett., 60(13), 940-943 (2019).
10.1016/j.tetlet.2019.02.044

A Panchromatic Electrochromic Device Composed of Ru(II)/Fe(II)-Based Heterometallo-Supramolecular Polymer,
L.-Y. Hsiao, T.-H. Chang, H.-C. Lu, Y.-C. Wang, Y.-A. Lu, K.-C. Ho, M. Higuchi,
J. Mater. Chem. C, 7(25), 7554-7562 (2019). (Selected to back cover)
10.1039/C9TC01452G

DNA-Binding, Cytotoxicity and Apoptosis Induction of Pt/Fe-Based Heterometallo-Supramolecular Polymer for Anticancer Drug Application,
U. Rana, C. Chakraborty, M. Kanao, H. Morita, T. Minowa, M. Higuchi,
J. Organomet. Chem., 891, 28-34 (2019).
10.1016/j.jorganchem.2019.03.021

Electrochromic Devices Using Fe(II)-Based Metallo-Supramolecular Polymer: Introduction of Ionic Liquid as Electrolyte to Enhance the Thermal Stability,
S. Mondal, T. Yoshida, M. Higuchi,
J. Soc. Inf. Display, 27(11), 661-666 (2019). (Special selection paper. Best of International Display Workshops 2018) (Selected to front cover)
10.1002/jsid.833

Thermally Stable Electrochromic Devices Using Fe(II)-Based Metallo-Supramolecular Polymer,
S. Mondal, T. Yoshida, U. Rana, M. K. Bera, M Higuchi,
Sol. Energy Mater. Sol. Cells, 200, 110000(1-8) (2019).
10.1016/j.solmat.2019.110000

M. Higuchi,
Metallo-Supramolecular Polymers: Synthesis, Properties, and Device Applications, NIMS Monograph Series (Springer 2019).

Chapter 13. Metallo-Supramolecular Polymers with Electrochromic Properties,
M. Higuchi,
Electrochromic Smart Materials, RSC Smart Materials Series (RSC Publishing 2019) 406-429.

2章メタロ超分子ポリマー (pp. 14-23)
17章グラデーション変化する調光ガラス (pp. 172-181)
樋口昌芳
エレクトロクロミックデバイスの開発最前線（CMC出版、2019).

[MN₆]_n (M=Fe(II), Co(II), Ru(II))
樋口昌芳
錯体化合物事典（朝倉書店、2019）448.
2018年の論文: Diversity in Design of Electrochromic Devices with Metallo-Supramolecular Polymer: Multi-Patterned and Tube-Shaped Displays,
T. Yoshida, M. Higuchi,
J. Photopolym. Sci. Technol., 31(3), 343-347 (2018).
10.2494/photopolymer.31.343

Modulation of a Coordination Structure in Europium(III)-Based Metallo-Supramolecular Polymer for High Proton Conduction,
Y. S L V Narayana, C. Chakraborty, U. Rana, Y. Ninomiya, T. Yoshida, M. Higuchi,
RSC Adv., 8(65), 37193–37199 (2018). (Open access)
10.1039/c8ra07405d

Long Chain Effects on DNA-Binding and Cytotoxicity to Cancer Cells in Metallo-Supramolecular Oligomers,
U. Rana, M. D. Hossain, C. Chakraborty, R. Nagano, H. Morita, S. Hattori, T. Minowa, M. Higuchi,
ChemistrySelect, 3(26), 7586-7591 (2018).
10.1002/slct.201800961

Electrochromic Os(II)-Based Metallo-Supramolecular Polymers,
M. K. Bera, C. Chakraborty, U. Rana, M. Higuchi,
Macromol. Rapid Commun., 39(22), 1800415(1-6) (2018). (Selected to back cover)
10.1002/marc.201800415
[The most cited paper of the year]
[One of the most cited papers]

Slow Magnetic Relaxation in a Tb(III)-Based Coordination Polymer,
T. Yoshida, Y. S L V Narayana, H. Abe, M. Higuchi,
Dalton Trans., 47(45), 16066-16071 (2018). (Selected to outside back cover, Open access)
10.1039/c8dt03125h
2017年の論文／著書: Effect of Metal-Metal Distance in Ni(II)-Based Metallo-Supramolecular Polymers on DNA Binding Affinity and Cytotoxicity,
M. D. Hossain, U. Rana, C. Chakraborty, J. Li, R. Nagano, T. Minowa, M. Higuchi,
RSC Adv., 7(60), 38008-38013 (2017). (Selected for Editors' Collection focusing on Supramolecular Chemistry 2019, 2020) (Open access)
10.1039/C7RA05644C

One-Dimensional Anhydrous Proton Conducting Channels Formation at High Temperature in a Pt(II)-Based Metallo-Supramolecular Polymer and Imidazole System,
C. Chakraborty, U. Rana, R. K. Pandey, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 9(15), 13406-13414 (2017).
10.1021/acsami.6b12963
[The most cited paper of the year]

Inert Layered Silicate Improves the Electrochemical Responses of a Metal Complex Polymer,
M. Eguchi, M. Momotake, F. Inoue, T. Oshima, K. Maeda, M. Higuchi,
ACS Appl. Mater. Interfaces, 9(40), 35498–35503 (2017).
10.1021/acsami.7b13311

4.3 電気で色が変わる高分子の開発とディスプレイ応用
樋口昌芳
科学立国日本を築く Part II　次代を拓く気鋭の研究者たち（日刊工業新聞社、2017）145-152.
2016年の論文／著書: Electrochemically Switchable Photoluminescence of Anionic Dye in Cationic Metallo-Supramolecular Polymer,
T. Suzuki, T. Sato, J. Zhang, M. Kanao, M. Higuchi, H. Maki,
J. Mater. Chem. C, 4, 1594-1598 (2016). (Selected to outside front cover)
10.1039/C5TC03071D

An Insight into Ion-Conduction Phenomenon of Gold Nanocluster Ligand Based Metallo-Supramolecular Polymers,
R. K. Pandey, C. Chakraborty, U. Rana, S. Moriyama, M. Higuchi,
J. Mater. Chem. A, 4, 4398-4401 (2016).
10.1039/C5TA10246D

Synthesis of Ni-Based Metallo-Supramolecular Polymer with Bis-NNO-Tridentate Ligand for Electrochromic Devices,
M. Kanao, M. Higuchi,
J. Photopolym. Sci. Technol., 29, 295-300 (2016).
10.2494/photopolymer.29.295

Geometrically Isomeric Pt(II)/Fe(II)-Based Heterometallo-Supramolecular Polymers with Organometallic Ligands for Electrochromism and Electrochemical Switching of Raman Scattering,
C. Chakraborty, R. K. Pandey, U. Rana, M. Kanao, S. Moriyama, M. Higuchi,
J. Mater. Chem. C, 4, 9428-9437 (2016). (Selected to outside back cover, Open access)
10.1039/C6TC02929A
[The most cited paper of the year]
[One of the most cited papers]

Solvent Effect on Electrochemical Properties of a Co(II)-Based Metallo-Supramolecular Polymer Film,
C.-Y. Hsu, J. Zhang, S. Moriyama, M. Higuchi,
Macromol. Symp., 363, 12-19 (2016).
10.1002/masy.201500136

Proton Conductive Nanosheets Formed by Alignment of Metallo-Supramolecular Polymers,
R. K. Pandey, U. Rana, C. Chakraborty, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 8, 13526-13531 (2016).
10.1021/acsami.6b02393

A Co(II)-Based Metallo-Supramolecular Polymer as a Novel Matrix of Enzyme Immobilization for Electrochemical Glucose Biosensing,
C.-Y. Hsu, T. Sato, S. Moriyama, M. Higuchi,
Eur. Polym. J., 83, 499-506 (2016).
10.1016/j.eurpolymj.2016.06.007

Selective DNA Recognition and Cytotoxicity of Water Soluble Helical Metallosupramolecular Polymers,
U. Rana, C. Chakraborty, R. K. Pandey, M. D. Hossain, R. Nagano, H. Morita, S. Hattori, T. Minowa, M. Higuchi,
Bioconjugate Chem., 27, 2307–2314 (2016).
10.1021/acs.bioconjchem.6b00255

Chapter 12. Metallo-Supramolecular Polymers: Synthesis, Properties and Device Fabrication,
M. Higuchi,
Intelligent Nanosystems for Energy, Information and Biological Technologies (Springer 2016) 217-248.
2015年の論文／著書: Effect of a Three-Dimensional Hyperbranched Structure to Ionic Conduction of Metallo-Supramolecular Polymers,
R. K. Pandey, M. D. Hossain, T. Sato, U. Rana, S. Moriyama, M. Higuchi,
RSC Adv., 5, 49224-49230 (2015).
10.1039/c5ra07217d

Proton Conduction in Mo(VI)-Based Metallo-Supramolecular Polymers,
R. K. Pandey, M. D. Hossain, C. Chakraborty, S. Moriyama, M. Higuchi,
Chem. Commun., 51, 11012-11014 (2015). (Selected to back cover)
10.1039/c5cc03634h

Synthesis of Metallo-Supramolecular Polymers with Bis-NNN-Tridentate Ligand for Electrochromic Devices,
M. Kanao, M. Higuchi,
J. Photopolym. Sci. Technol., 28, 363-368 (2015).
10.2494/photopolymer.28.363

Nano Molar Detection of Cd(II) Ions by Luminescent Metallo-Supramolecular Polymer Formation,
M. D. Hossain, R. K. Pandey, U. Rana, M. Higuchi,
J. Mater. Chem. C, 3, 12186-12191 (2015). (Selected to back cover)
10.1039/c5tc02734a

Black-to-Transmissive Electrochromism with Visible-to-Near-Infrared Switching of a Co(II)-Based Metallo-Supramolecular Polymer for Smart Window and Digital Signage Applications,
C.-Y. Hsu, J. Zhang, T. Sato, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 7, 18266-18272 (2015).
10.1021/acsami.5b02990
[The most cited paper of the year]
[One of the most cited papers]

Platinum(II)-Based Metallo-Supramolecular Polymer with Controlled Unidirectional Dipoles for Tunable Rectification,
C. Chakraborty, R. K. Pandey, M. D. Hossain, Z. Futera, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 7, 19034-19042 (2015).
10.1021/acsami.5b03434

Printed Multi-Color High-Contrast Electrochromic Devices,
B.-H. Chen, S.-Y. Kao, C.-W. Hu, M. Higuchi, K.-C. Ho, Y.-C. Liao,
ACS Appl. Mater. Interfaces, 7, 25069-25076 (2015).
10.1021/acsami.5b08061
[One of the most cited papers]

有機／金属ハイブリッドポリマーを用いたスマートウインドウの開発
樋口昌芳
遮熱・断熱材料の設計、性能評価と応用（技術情報協会、2015）174-182.
2014年の論文: Real-Time Humidity-Sensing Properties of Ionically Conductive Ni(II)-Based Metallo-Supramolecular Polymers,
R. K. Pandey, M. D. Hossain, S. Moriyama, M. Higuchi,
J. Mater. Chem. A, 2, 7618-7618 (2014). (Selected to inside front cover)
10.1039/c4ta00884g

Anion Effects to Electrochromic Properties of Ru-based Metallo-Supramolecular Polymers,
J. Zhang, C.-Y. Hsu, M. Higuchi,
J. Photopolym. Sci. Technol., 27, 297-300 (2014).
10.2494/photopolymer.27.297

メタロ超分子ポリマーの分子設計と電子・光機能
Design of Metallo-Supramolecular Polymers with Electronic and Optical Properties,
M. Higuchi,
高分子論文集, 71, 624-629 (2014).
10.1295/koron.71.624

Selective Edge Modification in Graphene and Graphite by Chemical Oxidation,
M. Yang, S. Moriyama, M. Higuchi,
J. Nanosci. Nanotechnol., 14, 2974-2978 (2014).
10.1166/jnn.2014.8578

Three-Dimensional Fe(II)-Based Metallo-Supramolecular Polymers with Electrochromic Properties of Quick Switching, Large Contrast, and High Coloration Efficiency,
C.-W. Hu, T. Sato, J. Zhang, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 6, 9118-9125 (2014).
10.1021/am5010859
[One of the most cited papers]

Synthesis of Metallo-Supramolecular Polymers with a Bis-ONO-tridentate Ligand by Coordination Programming,
M. Kanao, M. Higuchi,
Chem. Lett., 43, 1075-1077 (2014).
10.1246/cl.140253

A Heterometallo-Supramolecular Polymer with CuI and FeII Ions Introduced Alternately,
M. D. Hossain, J. Zhang, R. K. Pandey, T. Sato, M. Higuchi,
Eur. J. Inorg. Chem., 2014, 3763-3770 (2014).
10.1002/ejic.201402468

Stimuli-Responsive Metallo-Supramolecular Polymer Films: Design, Synthesis and Device Fabrication,
M. Higuchi,
J. Mater. Chem. C, 2, 9331-9341 (2014) (Feature article). (Selected to outside back cover)
10.1039/c4tc00689e
[The most cited paper of the year]
[One of the most cited papers]
2013年の論文: Metallo-Supramolecular Polymers: Versatile DNA Binding and Their Cytotoxicity,
J. Li, T. Murakami, M. Higuchi,
J. Inorg. Organomet. Polym. Mater., 23, 119-125 (2013).
10.1007/s10904-012-9752-2

A Green Color Copper-Based Metallo-Supramolecular Polymer: Synthesis, Structure, and Electrochromic Properties,
Md. Delwar Hossain, T. Sato, M. Higuchi,
Chem. Asian J., 8, 76-79 (2013).
10.1002/asia.201200668
[One of the most cited papers]

Multi-Colour Electrochromic Properties of Fe/Ru-Based Bimetallo-Supramolecular Polymers,
C.-W. Hu, T. Sato, J. Zhang, S. Moriyama, M. Higuchi,
J. Mater. Chem. C, 1, 3408-3413 (2013). (Selected to back cover)
10.1039/c3tc30440j
[The most cited paper of the year]
[One of the most cited papers]

An Alternately Introduced Heterometallo-Supramolecular Polymer: Synthesis and Solid-State Emission Switching by Electrochemical Redox,
T. Sato, M. Higuchi,
Chem. Commun., 49, 5256-5258 (2013). (Selected to back cover)
10.1039/c3cc41176a
[One of the most cited papers]

Ionic Conductivity of Ni(II)-Based Metallo-Supramolecular Polymers: Effects of Ligand Modification,
R. K. Pandey, M. D. Hossain, S. Moriyama, M. Higuchi,
J. Mater. Chem. A, 1, 9016-9018 (2013). (Selected to outside front cover)
10.1039/c3ta12080e

Fluorescent Colour Modulation in Zn(II)-Based Metallo-Supramolecular Polymer Films by Electronic-State Control of the Ligand,
T. Sato, R. K. Pandey, M. Higuchi,
Dalton Trans., 42, 16036-16042 (2013).
10.1039/c3dt51354h

Synthesis of Metallo-Supramolecular Polymers Using 5,5'-Linked Bis(1,10-Phenanthroline) Ligands,
M. D. Hossain, M. Higuchi,
Synthesis, 45, 753-758 (2013).
10.1055/s-0032-1316858

From Metal Complexes to Metallosupramolecular Polymers via Polycondensation: Synthesis, Structure and Electrochromic Properties of Co(III)- and Fe(III)-Based Metallosupramolecular Polymers with Aromatic Azo Ligands,
A. Bandyopadhyay, M. Higuchi,
Eur. Polym. J., 49, 1688-1697 (2013).
10.1016/j.eurpolymj.2013.03.015

Electrochemical Switching of Luminescence in a Ru(II)-Based Metallo-Supramolecular Polymer Device,
Y. Muronoi, J. Zhang, M. Higuchi, H. Maki,
Chem. Lett., 42, 761-763 (2013).
10.1246/cl.130158
2012年の論文: Chiral Phenylazomethine Cage,
R. Shomura, S. Higashibayashi, H. Sakurai, Y. Matsushita, A. Sato, M. Higuchi,
Tetrahedron Lett., 53(7), 783-785 (2012).
10.1016/j.tetlet.2011.11.141

A Vapoluminescent Eu-Based Metallo-Supramolecular Polymer,
T. Sato, M. Higuchi,
Chem. Commun., 48(41), 4947-4949 (2012). (Selected to back cover)
10.1039/c2cc30972f
[The most cited paper of the year]
[One of the most cited papers]
2011年の論文: Aromatic Macrocycle Containing Amine and Imine Groups: Intramolecular Charge-Transfer and Multiple Redox Behavior,
T. Ide, D. Takeuchi, K. Osakada, T. Sato, M. Higuchi,
J. Org. Chem., 76(22), 9504-9506 (2011).
10.1021/jo201650t

Gold Nanoparticles with Cyclic Phenylazomethines: One-pot Synthesis and Metal-Ion Sensing,
R. Shomura, K. J. Chung, H. Iwai, M. Higuchi,
Langmiur, 27(13), 7972-7975 (2011).
10.1021/la201067q

Synthesis of Unsymmetrical, Mono-substituted Bis-terpyridine Derivatives via Suzuki-Miyaura Cross-Coupling,
J. Li, T. Sato, H. Li, M. Higuchi,
Synthesis, 2011(9), 1361-1364 (2011).
10.1055/s-0030-1259986

Conjugation of Organic-Metallic Hybrid Polymers and Calf-Thymus DNA,
J. Li, Z. Futera, H. Li, Y. Tateyama, M. Higuchi,
Phys. Chem. Chem. Phys., 13(11), 4839-4841 (2011).
10.1039/c0cp02037k

Tuning of Nonvolatile Bipolar Memristive Switching in Co(III) Polymer with an Extended Azo Aromatic Ligand,
A. Bandyopadhyay, S. Sahu, M. Higuchi,
J. Am. Chem. Soc., 133(5), 1168-1171 (2011).
10.1021/ja106945v
[The most cited paper of the year]
[One of the most cited papers]

Synthesis of Thiophene-Capped [2]Rotaxanes,
T. Ikeda, M. Higuchi,
Tetrahedron, 67(17), 3046-3052 (2011).
10.1016/j.tet.2011.03.009

Electrochromic Properties of Polythiophene Polyrotaxane Film,
T. Ikeda, M. Higuchi,
Langmiur, 27(7), 4184-4189 (2011).
10.1021/la1043816
エレクトロクロミック機能を有する有機／金属ハイブリッドポリマーの開発と表示デバイスへの応用,
M. Higuchi,
有機合成化学協会誌, 69(3), 229-235 (2011).
10.5059/yukigoseikyokaishi.69.229
2010年の論文: Substituent Effects on Metallo-Supramolecular Coordination Polymers,
J. Li, M. Higuchi,
J. Inorg. Organomet. Polym. Mater., 20, 10-18 (2010).
10.1007/s10904-010-9331-3
[The most cited paper of the year]

Fluorescent Fe(II) Metallo-Supramolecular Polymers: Metal-Ion-Directed Self-Assembly of New Bisterpyridines Containing Triethylene Glycol Chains,
R. R. Pal, M. Higuchi, Y. Negishi, T. Tsukuda, D. G. Kurth,
Polym. J., 42, 336-341 (2010).
10.1038/pj.2010.3

有機/金属ハイブリッドポリマーにおける構造制御と電子・光機能制御,
M. Higuchi,
高分子論文集, 67(7), 368-374 (2010).
10.1295/koron.67.368
2009年の論文: Optically Active Metallo-Supramolecular Polymers Derived from Chiral Bis-terpyridines,
R. R. Pal, M. Higuchi, D. G. Kurth,
Org. Lett., 11(16), 3562-3565 (2009).
10.1021/ol901293r

Electrochromic Functions of Organic-Metallic Hybrid Polymers,
M. Higuchi,
J. Nanosci. Nanotechnol., 9(1), 51-58 (2009).
10.1166/jnn.2009.J034

Formation of (FeCl3)@phenylazomethine Dendrimer (DPA): Fine Control of the Release and Encapsulation of Fe Ions in Dendrimers,
K. Yamamoto, R. Nakajima, Y. Ochi, M. Tsuruta, M. Higuchi, A. Hida, J. Onoe,
Pure Appl. Chem., 81(12), 2253-2263 (2009).
10.1351/PAC-CON-09-01-13

Inclusion Complexation of Cyclobis(paraquat-p-phenylene) with Thiophene, Bithiophene and Terthiophene,
T. Ikeda, M. Higuchi, D. G. Kurth,
J. Incl. Phenom. Macrocycl. Chem., 64, 299-303 (2009).
10.1007/s10847-009-9566-1

From Thiophene [2]Rotaxane To Polythiophene Polyrotaxane,
T. Ikeda, M. Higuchi, D. G. Kurth,
J. Am. Chem. Soc., 131(26), 9158-9159 (2009).
10.1021/ja902992c
[One of the most cited papers]

Electrochromic Solid-State Devices Using Organic-Metallic Hybrid Polymers,
M. Higuchi, Y. Akasaka, T. Ikeda, A. Hayashi, D. G. Kurth,
J. Inorg. Organomet. Polym. Mater., 19, 74-78 (2009).
10.1007/s10904-008-9243-7
[One of the most cited papers]

Electrochromic Organic–Metallic Hybrid Polymers: Fundamentals and Device Applications,
M. Higuchi,
Polym. J., 41, 511-520 (2009).
10.1295/polymj.PJ2009053
[The most cited paper of the year]
[One of the most cited papers]

beta-Substituted Terthiophene [2]Rotaxanes,
T. Ikeda, M. Higuchi, D. G. Kurth,
Chem. Eur. J., 15(19), 4906-4913 (2009).
10.1002/chem.200802120
2008年の論文: Synthesis of pai-Conjugated Pyridine Ring Functionalized Bis-terpyridines with Efficient Green, Blue and Purple Emission,
F. Han, M. Higuchi, D. G. Kurth,
Tetraherdon, 64(38), 9108-9116 (2008).
10.1016/j.tet.2008.06.106

Synthesis of Tetrathiafulvalene-Functionalized Organic-Metal Hybrid Polymer,
T. Ikeda, M. Higuchi, D. G. Kurth,
Trans. Mater. Res. Soc. J., 33(2), 403-405 (2008).
10.14723/tmrsj.33.403

Syntheses of Novel Bis-terpyridine and Cyclic Phenylazomethine as Organic Modules in Organic-Metallic Hybrid Materials,
M. Higuchi, Y. Otsuka, R. Shomura, D. G. Kurth,
Thin Solid Films, 516(9), 2416-2420 (2008).
10.1016/j.tsf.2007.04.107

Preparation, Characterization, and Electrochromic Properties of Novel Co(II)-bis-2,2’:6’,2”-terpyridine Metallo-Supramolecular Polymers,
F. Han, M. Higuchi, Y. Akasaka, Y. Ohtsuka, D. G. Kurth,
Thin Solid Films, 516(9), 2469-2473 (2008).
10.1016/j.tsf.2007.04.144

Metallo-Supramolecular Polyelectrolytes Self-assembled from Various Pyridine Ring Substituted Bis-terpyridines and Metal Ions: Photophysical, Electrochemical and Electrochromic Properties,
F. Han, M. Higuchi, D. G. Kurth,
J. Am. Chem. Soc., 130(6), 2073-2081 (2008).
10.1021/ja710380a
[The most cited paper of the year]
[One of the most cited papers]

Thiophene Donor-Acceptor [2]Rotaxanes,
T. Ikeda, M. Higuchi, A. Sato, D. G. Kurth,
Org. Lett., 10(11), 2215-2218 (2008).
10.1021/ol800624c

Luminescence Properties of Metallo-Supramolecular Coordination Polymers Assembled from Pyridine Ring Functionalized Ditopic Bis-terpyridines and Ru(II) Ion,
F. Han, M. Higuchi, T. Ikeda, Y. Negishi, T. Tsukuda, D. G. Kurth,
J. Mater. Chem., 18(38), 4555-4560 (2008).
10.1039/b806930a
[One of the most cited papers]

有機/金属ハイブリッドポリマーの創製とエレクトロクロミック機能,
M. Higuchi,
高分子論文集, 65(6), 399-404 (2008).
10.1295/koron.65.399
2007年の論文: Metallo-Supramolecular Polymers Based on Functionalized Bis-terpyridines as Novel Electrochromic Materials,
F. Han, M. Higuchi, D. G. Kurth,
Adv. Mater., 19(22), 3928-3931 (2007).
10.1002/adma.200700931
[The most cited paper of the year]
[One of the most cited papers]

Heterometal Assembly in Dendritic Polyphenylazomethines,
K. Takanashi, A. Fujii, R. Nakajima, H. Chiba, M. Higuchi, Y. Einaga, K. Yamamoto,
Bull. Chem. Soc. Jpn, 80(8), 1563-1572 (2007).
10.1246/bcsj.80.1563
[One of the most cited papers]

Diverse Synthesis of Novel Bisterpyridines via Suzuki-Type Cross-Coupling,
F. Han, M. Higuchi, D. G. Kurth,
Org. Lett., 9(4), 559-562 (2007).
10.1021/ol062788h
[One of the most cited papers]

Synthesis of Organic-Metallic Hybrid Polymers Using Novel Bis-terpyridines Bearing Alkoxy Chains,
M. Higuchi, Y. Ohtsuka, Y. Akasaka, D. G. Kurth,
Trans. Mater. Res. Soc. J., 32(3), 759-762 (2007).
10.14723/tmrsj.32.763

Preferential Synthesis of Cyclic Pheylazomethines and Their Redox Behavior,
R. Shomura, M. Higuchi, D. G. Kurth,
Trans. Mater. Res. Soc. J., 32(3), 763-766 (2007).
10.14723/tmrsj.32.759

Synthesis of Novel Bis(terpyridyl)benzene Derivatives as Organic Modules in Organic-Metallic Hybrid Polymers,
M. Higuchi, Y. Ohtsuka, D. G. Kurth,
Trans. Mater. Res. Soc. J., 32(2), 425-428 (2007).
10.14723/tmrsj.32.425

Electrochemical Functions of Metallo-Supramolecular Nano-Materials,
M. Higuchi, D. G. Kurth,
Chem. Rec., 7(4), 203-209 (2007).
10.1002/tcr.20118
[One of the most cited papers]
2006年の論文: Synthesis of DPA Dendron Encapsulated Gold Clusters with Metal-Assembling Function,
Y. Men, M. Higuchi, K. Yamamoto,
Sci. Tech. Adv. Mater., 7, 139-144 (2006).
10.1016/j.stam.2005.10.007

Sequential Metal Ion Assembly in Cyclic Phenylazomethine,
M. Higuchi, R. Shomura, Y. Ohtsuka, A. Hayashi, K. Yamamoto, D. G. Kurth,
Org. Lett., 8(21), 4723-4726 (2006).
10.1021/ol061758b

The Solid-State Architecture of a Metallo-Supramolecular Polyelectrolyte,
U. Kolb, K. Buscher, C. A. Helm, A. Lindner, A. F. Thunemann, M. Menzel, M. Higuchi, D. G. Kurth,
Proc. Natl. Acad. Sci. USA, 103(27), 10202-10206 (2006).
10.1073/pnas.0601092103
[One of the most cited papers]

Metal Ion Assembly in Macromolecules,
M. Higuchi, A. Hayashi, D. G. Kurth,
J. Nanosci. Nanotechnol., 6(6), 1533-1551 (2006).
10.1166/jnn.2006.250

Modification and Electrochemical Properties of Poly(phenylazomethine) Derivatives,
M. Higuchi, A. Hayashi, K. Yamamoto,
Macromol. Symposia, 235(1), 121-126 (2006).
10.1002/masy.200650315

Functional Modules: Metal Ion Assembly in Novel Topological Poly(phenylazomethine)s,
M. Higuchi, D. G. Kurth, K. Yamamoto,
Thin Solid Films, 499(1-2), 234-241 (2006).
10.1016/j.tsf.2005.07.043

Synthesis of Ferrocene-Modified Phenylazomethine Dendrimers Possessing Redox Switching,
M. Suzuki, R. Nakajima, M. Tsuruta, M. Higuchi, Y. Einaga, K. Yamamoto,
Macromolecules, 39(1), 64-69 (2006).
10.1021/ma052268m

Synthesis and Chemical Degradation of Thermostable Polyamide with Imine Bond for Chemical Recycling,
H. Kanazawa, M. Higuchi, K. Yamamoto,
Macromolecules, 39(1), 138-144 (2006).
10.1021/ma0520141

Transition Metal Ions: Weak Links for Strong Polymers,
D. G. Kurth, M. Higuchi,
Soft Matter, 2(11), 915-927 (2006).
10.1039/B607485E
[The most cited paper of the year]
[One of the most cited papers]
2005年の論文: An Electric Cyclophane: Cavity Control Based on the Rotation of a Paraphenylene by Redox Switching,
H. Kanazawa, M. Higuchi, K. Yamamoto,
J. Am. Chem. Soc., 127(47), 16404-16405 (2005).
10.1021/ja055681i
[The most cited paper of the year]
[One of the most cited papers]

Phenylazomethine Dendrimer Complexes as Novel Hole-Transporting Materials of Organic Light-Emitting Diodes,
J.-S. Cho, K. Takanashi, M. Higuchi, K. Yamamoto,
Synth. Met., 150(1), 79-82 (2005).
10.1016/j.synthmet.2005.01.019
[One of the most cited papers]

Synthesis of Diphenylamine-Substituted Phenylazomethine Dendrimers and the Performance of Organic Light-Emitting Diodes,
J.-S. Cho, A. Kimoto, M. Higuchi, K. Yamamoto,
Macromol. Chem. Phys., 206(6), 635-641 (2005).
10.1002/macp.200400381

Novel Functional Groups with Fine-Controlled Metal Assembling Function,
K. Yamamoto, M. Higuchi, A. Kimoto, T. Imaoka, K. Masachika,
Bull. Chem. Soc. Jpn, 78(2), 349-355 (2005).
10.1246/bcsj.78.349

Fine-Control of Metal Ion Assembly in Novel Topological Poly(phenylazomethine)s,
M. Higuchi, K. Yamamoto,
Trans. Mater. Res. Soc. J., 30(3), 623-626 (2005).

Triarylamine Dendrimers with a Controlled Metal-Assembling Function for Organic EL Devices,
N. Satoh, J.-S. Cho, M. Higuchi, K. Yamamoto,
J. Photopolym. Sci. Technol., 18(1), 55-58 (2005).
10.2494/photopolymer.18.55

A High Energy Rechargeable Battery Based on a One-step Successive Two-electron Transfer Process,
K. Nishi, T. Nishiumi, M. Higuchi, K. Yamamoto,
Electrochem. Solid State Lett., 8(8), A382-A384 (2005).
10.1149/1.1940490
2004年の論文: Synthesis and Electroluminescence Properties of Novel Main Chain Poly(p-phenylenevinylene)s Possessing Pendant Phenylazomethine Dendrons as Metal Ligation Sites,
A. Kimoto, K. Masachika, J.-S. Cho, M. Higuchi, K. Yamamoto,
Chem. Mater., 16(26), 5706-5712 (2004).
10.1021/cm049241m

Fine-Control of Metal Assembling in Dendritic Polyphenylazomethines,
K. Yamamoto, M. Higuchi,
Polym. J., 36(8), 577-586 (2004).
10.1295/polymj.36.577

Synthesis of Asymmetrically Arranged Dendrimers with a Carbazole Dendron and a Phenylazomethine Dendron,
A. Kimoto, J.-S. Cho, M. Higuchi, K. Yamamoto,
Macromolecules, 37(15), 5531-5537 (2004).
10.1021/ma0499674
[The most cited paper of the year]
[One of the most cited papers]

The Class II/III Transition Electron Transfer on an Infrared Vibrational Time Scale for N,N'-Diphenyl-1,4-phenylenediamine Structures,
T. Nishiumi, Y. Nomura, Y. Chimoto, M. Higuchi, K. Yamamoto,
J. Phys. Chem. B, 108(23), 7992-8000 (2004).
10.1021/jp0492265

Novel pai-Conjugated Nano-Supramolecules Having Precise Metal-Assembling Function,
M. Higuchi, K. Yamamoto,
Bull. Chem. Soc. Jpn, 77(5), 853-874 (2004). (Award Accounts)
10.1246/bcsj.77.853

Efficient Synthesis of Poly(phenylazomethine) Dendrons Allowing Access to Higher Generation Dendrimers,
K. Takanashi, H. Chiba, M. Higuchi, K. Yamamoto,
Org. Lett., 6(11), 1709-1712 (2004).
10.1021/ol049656d
[One of the most cited papers]

Novel Poly(p-phenylenevinylene)s with a Phenylazomethine Dendron as a Metal-Collecting Site,
A. Kimoto, K. Masachika, J.-S. Cho, M. Higuchi, K. Yamamoto,
Org. Lett., 6(7), 1179-1182 (2004).
10.1021/ol0497741

First Redox Polymer Bearing One-Step Successive Two-Electron-Transfer Process Based on Redox Potential Inversion,
T. Nishiumi, Y. Chimoto, Y. Hagiwara, M. Higuchi, K. Yamamoto,
Macromolecules, 37(7), 2661-2664 (2004).
10.1021/ma035370x

Novel Carbazole Dendrimers Having a Metal Coordination Site as a Unique Hole-Transport Material,
A. Kimoto, J.-S. Cho, M. Higuchi, K. Yamamoto,
Macromol. Symposia, 209(1), 51-65 (2004).
10.1002/masy.200450504

Fine Control of the Release and Encapsulation of Fe Ions in Dendrimers Through Ferritin-Like Redox Switching,
R. Nakajima, M. Tsuruta, M. Higuchi, K. Yamamoto,
J. Am. Chem. Soc., 126(6), 1630-1631 (2004).
10.1021/ja037480p
[One of the most cited papers]

Fluorescence Switching Based on the Redox Reaction of Quinones Induced by Complexation with Rare-Earth Metals,
T. Kamimura, T. Nishiumi, M. Higuchi, K. Yamamoto,
Electrochem. Solid-State Lett., 7(2), H9-H11 (2004).
10.1149/1.1637562

Dendritic Polyphenylazomethines: Synthesis, Structures, and Metal-Assembling Functions,
K. Yamamoto, M. Higuchi,
Pure Appl. Chem., 76(7-8), 1399-1408 (2004).
10.1351/pac200476071399

精密金属集積高分子材料の創製と応用,
K. Yamamoto, M. Higuchi,
有機合成化学協会誌, 62(5), 433-439 (2004).
10.5059/yukigoseikyokaishi.62.433
2003年の論文: Intra-Molecular Energy Transfer Characteristics of Novel Oligo(thienylphenyl)amine Derivatives Having a Gradient Structure,
J. -S. Cho, Y. Kojima, N. Sato, M. Higuchi, K. Yamamoto,
Macromol. Chem. Phys., 204(18), 2175-2182 (2003).
10.1002/macp.200350078

Control of Stepwise Radial Complexation in Dendritic Polyphenylazomethines,
M. Higuchi, M. Tsuruta, H. Chiba, S. Shiki, K. Yamamoto,
J. Am. Chem. Soc., 125(33), 9988-9997 (2003).
10.1021/ja035608x
[One of the most cited papers]

Synthesis of Novel Carbazole Dendrimers Having a Metal Coordination Site,
A. Kimoto, J-S Cho, M. Higuchi, K. Yamamoto,
Chem. Lett., 32(8), 674-675 (2003).
10.1246/cl.2003.674

pai-Conjugated Polymers Exhibiting a Novel Doping Based on Redox of Side Chains,
T. Nishiumi, M. Higuchi, K. Yamamoto,
Macromolecules, 36(17), 6325-6332 (2003).
10.1021/ma025833j

Electron Transfer Rate on Mixed Valence States of Class II/III Transition for N,N'-Diphenyl-1,4-phenylenediamine Structures as a Polyaniline Unit,
T. Nishiumi, Y. Nomura, M. Higuchi, K. Yamamoto,
Chem. Phys. Lett., 378(1-2), 18-23 (2003).
10.1016/S0009-2614(03)01237-5

Novel Triarylamine Dendrimers as a Hole-transport Material with Controlled Metal-Assembling Function,
N. Satoh, J. -S. Cho, M. Higuchi, K. Yamamoto,
J. Am. Chem. Soc., 125(27), 8104-8105 (2003).
10.1021/ja034811p
[The most cited paper of the year]
[One of the most cited papers]

The First Electroresponsive Phenylazomethine Macrocycles: Highly Preferential Formation and Regular Molecular Packing,
M. Higuchi, H. Kanazawa, K. Yamamoto,
Org. Lett., 5(3), 345-347 (2003).
10.1021/ol0273755
2002年の論文: Stoichiometric Complexes between Cyclic Phenylazomethines and a Dialkyl Phosphate for Molecular Tiling at the Air-Water Interface,
K. Ariga, R. Tanaka, J. Kikuchi, M. Higuchi, K. Yamamoto,
J. Nanosci. Nanotechnol., 2(6), 669-674 (2002).
10.1166/jnn.2002.147

Oligophenylazomethines: Synthesis, Structure, Electrochemical Property and Photo-cyclization,
M. Higuchi, K. Yamamoto,
Polym. Adv. Technol., 13(10-12), 765-770 (2002).
10.1002/pat.255

Novel pai-Conjugated Polymers Exhibiting Conductive-Insulator Transition Based on the Redox of PDA Units through Electron Communication,
T. Nishiumi, M. Higuchi, K. Yamamoto,
Electrochem., 70(9), 668-670 (2002).
10.5796/electrochemistry.70.668

A Novel Synthetic Route of Redox-active Oligo(thio-1,4-phenylene) Derivatives via a Michael-type Addition,
K. Yamamoto, M. Higuchi, T. Nishiumi, H. Takai,
Bull. Chem. Soc. Jpn, 75(8), 1827-1832 (2002).
10.1246/bcsj.75.1827

Synthesis and Electrochemical Properties of Oligo- and Poly(thienylphenylamine)s,
K. Yamamoto, M. Higuchi, K. Uchida, Y. Kojima,
Macromolecules, 35(15), 5782-5788 (2002).
10.1021/ma011018c

Novel Linear and Hyperbranched Aromatic Polyamide with Phenylazomethine Units for Chemical Recycling,
K. Yamamoto, M. Higuchi, H. Kanazawa,
Chem. Lett., 31(7), 692-693 (2002).
10.1246/cl.2002.692

Stepwise Radial Complexation of Imine Groups in Phenylazomethine Dendrimers,
K. Yamamoto, M. Higuchi, S. Shiki, M. Tsuruta, H. Chiba,
Nature, 415, 509-511 (2002).
10.1038/415509a
[The most cited paper of the year]
[One of the most cited papers]

精密金属集積能を有するポリフェニルアゾメチン新ナノ構造体,
M. Higuchi, K. Yamamoto,
有機合成化学協会誌, 60(9), 869-877 (2002).
10.5059/yukigoseikyokaishi.60.869
2001年の論文: Controlled Cyclotrimerization in Hyperbranched Polymer Synthesis,
M. Higuchi, H. Kanazawa, M. Tsuruta, K. Yamamoto,
Macromolecules, 34(26), 8847-8850 (2001).
10.1021/ma0111461

First Synthesis of Phenylazomethine Dendrimer Ligands and Structural Studies,
M. Higuchi, S. Shiki, K. Ariga, K. Yamamoto,
J. Am. Chem. Soc., 123(19), 4414-4420 (2001).
10.1021/ja004239r
[The most cited paper of the year]
[One of the most cited papers]

Novel Synthesis of Electroresponsive Poly(thiophenylene) through a Michael-Type Addition,
K. Yamamoto, M. Higuchi, H. Takai, T. Nishiumi,
Org. Lett., 3(1), 131-134 (2001).
10.1021/ol0068501

Excellent Redox Properties of Poly(thienylphenylamine)s,
K. Yamamoto, M. Higuchi, K. Uchida, Y. Kojima,
Macromol. Rapid. Commun., 22(4), 266-270 (2001).
10.1002/1521-3927(20010201)22:4<266::AID-MARC266>3.0.CO;2-8
2000年の論文: Novel Phenylazomethine Dendrimers: Synthesis and Structural Properties,
M. Higuchi, S. Shiki, K. Yamamoto,
Org. Lett., 2(20), 3079-3082 (2000).
10.1021/ol006241t
[The most cited paper of the year]
[One of the most cited papers]

Selective Synthesis of Novel Cyclic Phenylazomethine Trimers,
M. Higuchi, A. Kimoto, S. Shiki, K. Yamamoto,
J. Org. Chem., 65(18), 5680-5684 (2000).
10.1021/jo000509c
[One of the most cited papers]
1999年の論文: Novel Cyclic Molecules: Selective Synthesis of Cyclic Phenylazomethines,
M. Higuchi, K. Yamamoto,
Org. Lett., 1(12), 1881-1883 (1999).
10.1021/ol990975s
[The most cited paper of the year]
[One of the most cited papers]
1998年の論文: A Novel Redox System Consisting of pai-Conjugated Polymers and Transition Metals,
T. Hirao, M. Higuchi, S. Yamaguchi,
Macromol. Symposia, 131(1), 59-68 (1998).
10.1002/masy.19981310109
[The most cited paper of the year]
1997年の論文 (D3): A Novel Synthetic Metal Catalytic System,
M. Higuchi, I. Ikeda, T. Hirao,
J. Org. Chem., 62(4), 1072-1078 (1997).
10.1021/jo9617575
[The most cited paper of the year]
[One of the most cited papers]

合成金属触媒システムの構築と特性,
M. Higuchi, T. Hirao,
高分子論文集, 54(10), 632-640 (1997).
10.1295/koron.54.632
1996年の論文 (D2): Construction of Palladium-Polypyrrole Catalytic System in the Wacker Oxidation,
M. Higuchi, S. Yamaguchi, T. Hirao,
Synlett, 1996(12), 1213-1214 (1996).
10.1055/s-1996-5722
[One of the most cited papers]

Redox Behavior of Polyaniline-Transition Metal Complexes in Solution,
M. Higuchi, D. Imoda, T. Hirao,
Macromolecules, 29(25), 8277-8279 (1996).
10.1021/ma960761f
[The most cited paper of the year]
[One of the most cited papers]
1995年の論文 (D1): A Novel Redox System for the Palladium(II)-Catalyzed Oxidation Based on Redox of Polyanilines,
T. Hirao, M. Higuchi, B. Hatano, I. Ikeda,
Tetrahedron Lett., 36(33), 5925-5928 (1995).
10.1016/0040-4039(95)01143-6
[The most cited paper of the year]
[One of the most cited papers]
1993年の論文 (M1): Doping Effect of Polyaniline Derivatives on Synthetic Metal Catalytic System for Dehydrogenative Oxidation of Benzylamine,
T. Hirao, M. Higuchi, Y. Ohshiro, I. Ikeda,
Chem. Lett., 22(11), 1889-1890 (1993).
10.1246/cl.1993.1889

A Novel Synthetic Metal Catalytic System for Dehydrogenative Oxidation Based on Redox of Polyaniline,
T. Hirao, M. Higuchi, I. Ikeda, Y. Ohshiro,
J. Chem. Soc., Chem. Commun., 1993(2), 194-195 (1993).
10.1039/C39930000194
[The most cited paper of the year]
[One of the most cited papers]

連絡先

Dr. Masayoshi HIGUCHI / 樋口昌芳
Tel: 029-860-4721
E-mail: HIGUCHI.Masayoshi(delete here)@nims.go.jp