Group | NIMS

Paper

h-Index 42
[The most cited paper of the year] in the following list is the most cited paper of the year
[One of the most cited papers] in the following list is one of the most cited 40 papers
Articles in 2025
Construction of Heterometallic Coordination Nanosheets Comprising Both Inert and Labile Metal Ions Together via Metalloligand Approach
M. K. Bera, S. Sarmah, A. Maity, M. Higuchi, Inorg. Chem. (2025) ASAP. (Open Access)
10.1021/acs.inorgchem.5c00224
Published online: 3 April 2025
Published in issue:

Articles in 2024
Triple-Band Electrochromic Switching among Visible (400–750 nm), NearIR-I (750–1000 nm), and NearIR-II (1000–1600 nm) Regions with Triple-Redox-Active Metallosupramolecular Polymers
D. C. Santra, S. Mondal, B. Prusti, M. Higuchi
ACS Appl. Opt. Mater., 2(6), 1117–1127 (2024).
10.1021/acsaom.4c00108
Published online: 21 May 2024
Published in issue: 28 June 2024

Microwave-Assisted Quick Synthesis of Ru(II)-Based Metallosupramolecular Polymer for Improved Electrochromic Properties
U. Rana, D. C. Santra, B. Prusti, C. Chakraborty, T. Ikeda, Y. Saito, K. Takeuchi, R. Nagahata, M. Higuchi
Macromol. Chem. Phys., 225(5), 2300381 (2024). (Selected to cover)
10.1002/macp.202300381
Published online: 8 January 2024
Published in issue: March 2024

In Situ Film Growth of Metallosupramolecular Polymer via Electropolymerization and Its Application as Electrochromic Film
C-W. Hu, S. Jena, T. Sato, J. Zhang, S. Moriyama, M. Higuchi
ACS Appl. Polym. Mater., 6(1), 441-447 (2024). (Selected to supplementary cover)
10.1021/acsapm.3c01937
Published online: 18 December 2023
Published in issue: 12 January 2024

Heterometallic Supramolecular Polymers: from Synthesis to Properties and Applications
M. K. Bera, S. Sarmah, D. C. Santra, M. Higuchi
Coord. Chem. Rev., 501, 215573 (2024).
10.1016/j.ccr.2023.215573

Articles in 2023
Highly Durable Electrochromic Devices for More than 100,000 Cycles with Fe(II)-Based Metallo-Supramolecular Polymer by Optimization of the Device Conditions
S. Mondal, S. Roy, Y. Fujii, M. Higuchi
ACS Appl. Electron. Mater., 5(12), 6677–6685 (2023). (Selected to supplementary cover)
10.1021/acsaelm.3c01143
Published online: 5 December 2023
Published in issue: 26 December 2023

Electrochromic Ru-Based Metallo-Supramolecular Polymer with Layered Inorganic-Organic Hybrid Nanocomposite for Improved Electrochemical Properties
K. Fujii, D. C. Santra, M. K. Bera, T. Wakahara, R. Nagahata, M. Higuchi
ACS Appl. Polym. Mater., 5(11), 8808-8821 (2023). (Selected to supplementary cover)
10.1021/acsapm.3c00837
Published online: 19 October 2023
Published in issue: 10 November 2023

Reversible Electrochromic/Electrofluorochromic Dual Switching in Zn(II)-Based Metallo-Supramolecular Polymer Film
S. Mondal, D. C. Santra, S. Roy, Y. S. L. V. Narayana, T. Yoshida, Y. Ninomiya, M. Higuchi
ACS Appl. Mater. Interfaces, 15(36), 42912–42919 (2023).
10.1021/acsami.3c06673
Published online: 30 August 2023
Published in issue: 13 September 2023

Flexible Multicolor Rewritable Paper Coated with Metallo-supramolecular Polymers for Electrochromic Printing and Natural Erasing by Humidity
J. Zhang, S. R. Jena, M. Higuchi
ACS Appl. Polym. Mater., 5(9), 6950–6957 (2023). (Selected to supplementary cover)
10.1021/acsapm.3c00991
Published online: 23 August 2023
Published in issue: 8 September 2023

Recent Progress on Metallo-Supramoleculear Polymers and the Electrochromic Devices Fabrication
Masayoshi Higuchi
Journal of Synthetic Organic Chemistry, Japan, 81(11), 1089-1095 (2023). Open Access

Articles in 2022
Electrochromic Coordination Polymers,
M. Higuchi,
Bull. Jpn. Soc. Coord. Chem., 79, 68-77 (2022). (Award Account, Open Access)
10.4019/bjscc.79.68
Publication Date: June 6, 2022

Rational Synthesis of Ruthenium-Based Metallo-Supramolecular Polymers as Heterogeneous Catalysts for Catalytic Transfer Hydrogenation of Carbonyl Compounds,
Z.-J, Gong, Y. S. L. V. Narayana, Y.-C. Lin, W.-H. Huang, W.-N. Su, Y.-P. Li, M. Higuchi, W.-Y. Yu,
Appl. Catal. B, 312, 121383(1-12) (2022).
10.1016/j.apcatb.2022.121383
Published online: April 8, 2022
[The most cited paper of the year]

Nanocomposites of Fe(II)-Based Metallo-Supramolecular Polymer and a Layered Inorganic–Organic Hybrid for Improved Electrochromic Materials,
K. Fujii, M. K. Bera, D. C. Santra, M. Higuchi,
Polymers (Special Issue "Applications of Polymers in Energy and Environmental Sciences"), 14(5), 915(1-16) (2022). (Open Access)
10.3390/polym14050915
Published online: February 25, 2022

Articles in 2021
Ru(II)-Based Metallo-Supramolecular Polymer with Tetrakis(N-methylbenzimidazolyl)bipyridine for a Durable, Nonvolatile, and Electrochromic Device Driven at 0.6 V,
D. C. Santra, S. Mondal, T. Yoshida, Y. Ninomiya, M. Higuchi,
ACS Appl. Mater. Interfaces, 13(26), 31153–31162 (2021).
10.1021/acsami.1c07275

Designed, Flexible Electrochromic Display Device with Fe(II)-Based Metallo-Supramolecular Polymer Using Mechanically Etched ITO Film,
M. Higuchi, Y. Fujii,
J. Photopolym. Sci. Technol., 34(2), 175–180 (2021). (Open Access)
10.2494/photopolymer.34.175

Designed Electrochromic Display Devices with Ru(II)-Based Metallo-Supramolecular Polymer For Experience-Based Exhibits at Ehime Prefectural Science Museum,
M. Higuchi, Y. Fujii, Y. Hisamatsu,
ITE Trans. Media Technol. Appl., 9(4), 228-233 (2021). (Open Access)
10.3169/mta.9.228

Durable Electrochromic Devices Driven at 0.8 V by Complementary Chromic Combination of Metallo-Supramolecular Polymer and Prussian Blue Analogues for Smart Windows with Low-Energy Consumption,
H.-C. Lu, L.-Y. Hsiao, S.-Y. Kao, Y. Seino, D. C. Santra, K.-C. Ho, M. Higuchi,
ACS Appl. Electron. Mater., 3(5), 2123–2135 (2021).
10.1021/acsaelm.1c00132
[The most cited papers of the year]

One-Step Synthesis of Three-Dimensionally Hyperbranched Fe(II)-Based Metallo-Supramolecular Polymer Using Asymmetrical Ditopic Ligand for Durable Electrochromic Films with Wide Absorption, Large Optical Contrast, and High Coloration Efficiency,
Y. S. L. V. Narayana, S. Mondal, U. Rana, Y. Ninomiya, D. C. Santra, T. Yoshida, M. Higuchi,
ACS Appl. Electron. Mater., 3(5), 2044–2055 (2021).
10.1021/acsaelm.1c00061

Stepwise Introduction of Three Different Transition Metals in Metallo-Supramolecular Polymer for Quad-Color Electrochromism,
M. K. Bera, Y. Ninomiya, M. Higuchi,
Commun. Chem., 4, 56(1-12) (2021). (Open Access)
10.1038/s42004-021-00495-1
Published on May 3, 2021.
[The most cited papers of the year]

Articles in 2020
Dual-Redox System of Metallo-supramolecular Polymers for Visible-to-Near-IR Modulable Electrochromism and Durable Device Fabrication,
S. Mondal, D. C. Santra, Y. Ninomiya, T. Yoshida, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(52), 58277–58286 (2020). (Selected to supplementary cover)
10.1021/acsami.0c18109

Synthesis of Alternated Heterobimetallic Supramolecular Polymer Based on Ru(II) and Fe(II),
M. K. Bera, Y. Ninomiya, M. Higuchi,
Molecules (Special Issue "Coordination Programming for Electro-, Magneto-, and Photofunctional Molecular Systems: A Theme Issue in Honor of Prof. Dr. Hiroshi Nishihara"), 25(22), 5261(1-9) (2020). (Open access)
10.3390/molecules25225261

Durable Supercapattery Film with Dual-Branched Dense Hexagonal Fe(II)-Based Coordination Nanosheets for Flexible Power Sources,
S. Mondal, Y. Ninomiya, M. Higuchi,
ACS Appl. Energy Mater., 3(11), 10653–10659 (2020).
10.1021/acsaem.0c01720

Green-to-Black Electrochromic Copper(I)-Based Metallo-Supramolecular Polymer with a Perpendicularly Twisted Structure,
M. D. Hossain, C. Chakraborty, U. Rana, S. Mondal, H.-J. Holdt, M. Higuchi,
ACS Appl. Polym. Mater., 2(11), 4449-4454 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00559

Luminescent Amphiphilic Nanogels by Terpyridine-Zn(II) Ion Complexation of Polymeric Micelles,
D. A. Saleh, U. Rana, M. Higuchi, A. Sosnik,
Mater. Today Chem., 18, 100359(1-13) (2020).
10.1016/j.mtchem.2020.100359

Helical Fe(II)-Based Metallo-Supramolecular Polymers: Effect of Crown Ether Groups Located outside the Helix on Hydrous Proton Channel Formation,
C. Chakraborty, U. Rana, Y. S L V Narayana, S. Moriyama, M. Higuchi,
ACS Appl. Polym. Mater., 2(11), 4521-4530 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00611

One-Pot Synthesis of Three-Dimensionally Hyperbranched Eu/Fe-Based Heterometallo-Supramolecular Polymers as Thermally Tough Proton-Conducting Nanoparticles,
Y. S L V Narayana, U. Rana, C. Chakraborty, T. Yoshida, M. Higuchi,
ACS Appl. Polym. Mater., 2(11), 4439-4448 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00541

Multifunctional Pt(II)-Based Metallo-Supramolecular Polymer with Carboxylic Acid Groups: Electrochemical, Mechanochemical, Humidity, and pH Response,
C. Chakraborty, U. Rana, S. Moriyama, M. Higuchi,
ACS Appl. Polym. Mater., 2(9), 4149-4159 (2020). (Selected to supplementary cover)
10.1021/acsapm.0c00782

Flexible Rewritable Electrochromic Device with Handwriting Feature,
S.-Y. Peng, C.-H. Su, M. Higuchi, K.-C. Ho, Y.-C. Liao,
Sol. Energy Mater. Sol. Cells, 217, 110738(1-8) (2020).
10.1016/j.solmat.2020.110738

Dual-Branched Dense Hexagonal Fe(II)-Based Coordination Nanosheets with Red-to-Colorless Electrochromism and Durable Device Fabrication,
S. Mondal, Y. Ninomiya, T. Yoshida, T. Mori, M. K. Bera, K. Ariga, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(28), 31896-31903 (2020).
10.1021/acsami.0c05921

Electrochromic Os-Based Metallo-Supramolecular Polymer: Electronic State Tracking by in situ XAFS, IR, and Impedance Spectroscopies,
T. Yoshida, M. K. Bera, Y. S L V Narayana, S. Mondal, H. Abe, M. Higuchi,
RSC Adv., 10(41), 24691-24696 (2020). (Open access)
10.1039/D0RA03236K

Ni(II)-Based Metallosupramolecular Polymer with Carboxylic Acid Groups: A Stable Platform for Smooth Imidazole Loading and the Anhydrous Proton Channel Formation,
Y. S L V Narayana, T. Yoshida, M. K. Bera, S. Mondal, M. Higuchi,
ACS Omega, 5(24), 14796-14804 (2020). (Selected to supplementary cover, Open access)
10.1021/acsomega.0c01735

Electrochromic Fe(II)-Based Metallo-Supramolecular Polymers: Color Modulation by Spacer Modification in Bisterpyridine Ligand,
Y. Ninomiya, T. Yoshida, M. Higuchi,
Chem. Lett., 49(9), 1003-1005 (2020).
10.1246/cl.200307

Thermally Tough Electrochromic Devices with Metallo-Supramolecular Polymer: Investigation of Gel Electrolyte Component and Fabrication Process,
M. Kanao, Y. Seino, M. Higuchi,
J. Photopolym. Sci. Technol., 33(4), 405-412 (2020).
10.2494/photopolymer.33.405

Transparent Supercapacitor Display with Redox-Active Metallo-Supramolecular Polymer Films,
S. Mondal, T. Yoshida, S. Maji, K. Ariga, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(14), 16342-16349 (2020).
10.1021/acsami.9b23123

Molecular Level Assembly for High-Performance Flexible Electrochromic Energy Storage Devices,
G. Cai, J. Chen, J. Xiong, A. L.-S. Eh, J. Wang, M. Higuchi, P. S. Lee,
ACS Energy Lett., 5(4), 1159-1166 (2020).
10.1021/acsenergylett.0c00245
[The most cited paper of the year]
[One of the most cited papers]

Constructing Alternated Heterobimetallic [Fe(II)/Os(II)] Supramolecular Polymers with Diverse Solubility for Facile Fabrication of Voltage-Tunable Multicolor Electrochromic Devices,
M. K. Bera, Y. Ninomiya, M. Higuchi,
ACS Appl. Mater. Interfaces, 12(12), 14376-14385 (2020).
10.1021/acsami.9b21966

Reversible Four-Color Electrochromism Triggered by the Electrochemical Multi-Step Redox of Cr-Based Metallo-Supramolecular Polymers,
T. Yoshida, Y. Ninomiya, M. Higuchi,
RSC Adv., 10(18), 10904-10909 (2020). (Open access)
10.1039/d0ra00676a

Proton Conductivity of Metallo-Supramolecular Polymer Boosted by Lithium Ions,
Y. S L V Narayana, T. Yoshida, C. Chakraborty, M. K. Bera, M. Higuchi,
ACS Appl. Polym. Mater., 2(2), 326-334 (2020). (Selected to supplementary cover)
10.1021/acsapm.9b00818

Precise Synthesis of Alternate Fe(II)/Os(II)-Based Bimetallic Metallo-Supramolecular Polymer,
M. K. Bera, Y. Ninomiya, T. Yoshida, M. Higuchi,
Macromol. Rapid Commun. (Special Issue: 100 Years of Macromolecular Chemistry), 41(1), 1900384(1-4) (2020). (Selected to back cover, Free access)
10.1002/marc.201900384

Electrolyte Gated-Organic Field Effect Transistors Functionalized by Lipid Monolayers with Tunable pH Sensitivity for Sensor Applications,
T. P. Nguy, R. Hayakawa, V. Kilinc, M. Petit, Y. S L V Narayana, M. Higuchi, J.-M. Raimundo, A. Charrier, Y. Wakayama,
Appl. Phys. Express, 13, 011005(1-5) (2020).
10.7567/1882-0786/ab5322

Articles and Books in 2019
Construction of Coordination Nanosheets Based on Tris(2,2'-Bipyridine)-Iron (Fe2+) Complexes as Potential Electrochromic Materials,
M. K. Bera, T. Mori, T. Yoshida, K. Ariga, M. Higuchi,
ACS Appl. Mater. Interfaces, 11(12), 11893-11903 (2019). (Selected to supplementary cover)
10.1021/acsami.8b22568
[The most cited paper of the year]
[One of the most cited papers]

Efficient White-Light-Emission from a Heterometallo-Supramolecular Polymer with Eu(III) and Zn(II) Ions Introduced Alternately,
T. Sato, M. Higuchi,
Tetrahedron Lett., 60(13), 940-943 (2019).
10.1016/j.tetlet.2019.02.044

A Panchromatic Electrochromic Device Composed of Ru(II)/Fe(II)-Based Heterometallo-Supramolecular Polymer,
L.-Y. Hsiao, T.-H. Chang, H.-C. Lu, Y.-C. Wang, Y.-A. Lu, K.-C. Ho, M. Higuchi,
J. Mater. Chem. C, 7(25), 7554-7562 (2019). (Selected to back cover)
10.1039/C9TC01452G

DNA-Binding, Cytotoxicity and Apoptosis Induction of Pt/Fe-Based Heterometallo-Supramolecular Polymer for Anticancer Drug Application,
U. Rana, C. Chakraborty, M. Kanao, H. Morita, T. Minowa, M. Higuchi,
J. Organomet. Chem., 891, 28-34 (2019).
10.1016/j.jorganchem.2019.03.021

Electrochromic Devices Using Fe(II)-Based Metallo-Supramolecular Polymer: Introduction of Ionic Liquid as Electrolyte to Enhance the Thermal Stability,
S. Mondal, T. Yoshida, M. Higuchi,
J. Soc. Inf. Display, 27(11), 661-666 (2019). (Special selection paper. Best of International Display Workshops 2018) (Selected to front cover)
10.1002/jsid.833

Thermally Stable Electrochromic Devices Using Fe(II)-Based Metallo-Supramolecular Polymer,
S. Mondal, T. Yoshida, U. Rana, M. K. Bera, M Higuchi,
Sol. Energy Mater. Sol. Cells, 200, 110000(1-8) (2019).
10.1016/j.solmat.2019.110000

M. Higuchi,
Metallo-Supramolecular Polymers: Synthesis, Properties, and Device Applications, NIMS Monograph Series (Springer 2019).

Chapter 13. Metallo-Supramolecular Polymers with Electrochromic Properties,
M. Higuchi,
Electrochromic Smart Materials, RSC Smart Materials Series (RSC Publishing 2019) 406-429.

Articles in 2018
Diversity in Design of Electrochromic Devices with Metallo-Supramolecular Polymer: Multi-Patterned and Tube-Shaped Displays,
T. Yoshida, M. Higuchi,
J. Photopolym. Sci. Technol., 31(3), 343-347 (2018).
10.2494/photopolymer.31.343

Modulation of a Coordination Structure in Europium(III)-Based Metallo-Supramolecular Polymer for High Proton Conduction,
Y. S L V Narayana, C. Chakraborty, U. Rana, Y. Ninomiya, T. Yoshida, M. Higuchi,
RSC Adv., 8(65), 37193–37199 (2018). (Open access)
10.1039/c8ra07405d

Long Chain Effects on DNA-Binding and Cytotoxicity to Cancer Cells in Metallo-Supramolecular Oligomers,
U. Rana, M. D. Hossain, C. Chakraborty, R. Nagano, H. Morita, S. Hattori, T. Minowa, M. Higuchi,
ChemistrySelect, 3(26), 7586-7591 (2018).
10.1002/slct.201800961

Electrochromic Os(II)-Based Metallo-Supramolecular Polymers,
M. K. Bera, C. Chakraborty, U. Rana, M. Higuchi,
Macromol. Rapid Commun., 39(22), 1800415(1-6) (2018). (Selected to back cover)
10.1002/marc.201800415
[The most cited paper of the year]
[One of the most cited papers]

Slow Magnetic Relaxation in a Tb(III)-Based Coordination Polymer,
T. Yoshida, Y. S L V Narayana, H. Abe, M. Higuchi,
Dalton Trans., 47(45), 16066-16071 (2018). (Selected to outside back cover, Open access)
10.1039/c8dt03125h

Articles in 2017
Effect of Metal-Metal Distance in Ni(II)-Based Metallo-Supramolecular Polymers on DNA Binding Affinity and Cytotoxicity,
M. D. Hossain, U. Rana, C. Chakraborty, J. Li, R. Nagano, T. Minowa, M. Higuchi,
RSC Adv., 7(60), 38008-38013 (2017). (Selected for Editors' Collection focusing on Supramolecular Chemistry 2019, 2020) (Open access)
10.1039/C7RA05644C

One-Dimensional Anhydrous Proton Conducting Channels Formation at High Temperature in a Pt(II)-Based Metallo-Supramolecular Polymer and Imidazole System,
C. Chakraborty, U. Rana, R. K. Pandey, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 9(15), 13406-13414 (2017).
10.1021/acsami.6b12963
[The most cited paper of the year]

Inert Layered Silicate Improves the Electrochemical Responses of a Metal Complex Polymer,
M. Eguchi, M. Momotake, F. Inoue, T. Oshima, K. Maeda, M. Higuchi,
ACS Appl. Mater. Interfaces, 9(40), 35498–35503 (2017).
10.1021/acsami.7b13311

Articles and Book in 2016
Electrochemically Switchable Photoluminescence of Anionic Dye in Cationic Metallo-Supramolecular Polymer,
T. Suzuki, T. Sato, J. Zhang, M. Kanao, M. Higuchi, H. Maki,
J. Mater. Chem. C, 4, 1594-1598 (2016). (Selected to outside front cover)
10.1039/C5TC03071D

An Insight into Ion-Conduction Phenomenon of Gold Nanocluster Ligand Based Metallo-Supramolecular Polymers,
R. K. Pandey, C. Chakraborty, U. Rana, S. Moriyama, M. Higuchi,
J. Mater. Chem. A, 4, 4398-4401 (2016).
10.1039/C5TA10246D

Synthesis of Ni-Based Metallo-Supramolecular Polymer with Bis-NNO-Tridentate Ligand for Electrochromic Devices,
M. Kanao, M. Higuchi,
J. Photopolym. Sci. Technol., 29, 295-300 (2016).
10.2494/photopolymer.29.295

Geometrically Isomeric Pt(II)/Fe(II)-Based Heterometallo-Supramolecular Polymers with Organometallic Ligands for Electrochromism and Electrochemical Switching of Raman Scattering,
C. Chakraborty, R. K. Pandey, U. Rana, M. Kanao, S. Moriyama, M. Higuchi,
J. Mater. Chem. C, 4, 9428-9437 (2016). (Selected to outside back cover, Open access)
10.1039/C6TC02929A
[The most cited paper of the year]
[One of the most cited papers]

Solvent Effect on Electrochemical Properties of a Co(II)-Based Metallo-Supramolecular Polymer Film,
C.-Y. Hsu, J. Zhang, S. Moriyama, M. Higuchi,
Macromol. Symp., 363, 12-19 (2016).
10.1002/masy.201500136

Proton Conductive Nanosheets Formed by Alignment of Metallo-Supramolecular Polymers,
R. K. Pandey, U. Rana, C. Chakraborty, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 8, 13526-13531 (2016).
10.1021/acsami.6b02393

A Co(II)-Based Metallo-Supramolecular Polymer as a Novel Matrix of Enzyme Immobilization for Electrochemical Glucose Biosensing,
C.-Y. Hsu, T. Sato, S. Moriyama, M. Higuchi,
Eur. Polym. J., 83, 499-506 (2016).
10.1016/j.eurpolymj.2016.06.007

Selective DNA Recognition and Cytotoxicity of Water Soluble Helical Metallosupramolecular Polymers,
U. Rana, C. Chakraborty, R. K. Pandey, M. D. Hossain, R. Nagano, H. Morita, S. Hattori, T. Minowa, M. Higuchi,
Bioconjugate Chem., 27, 2307–2314 (2016).
10.1021/acs.bioconjchem.6b00255

Chapter 12. Metallo-Supramolecular Polymers: Synthesis, Properties and Device Fabrication,
M. Higuchi,
Intelligent Nanosystems for Energy, Information and Biological Technologies (Springer 2016) 217-248.

Articles in 2015
Effect of a Three-Dimensional Hyperbranched Structure to Ionic Conduction of Metallo-Supramolecular Polymers,
R. K. Pandey, M. D. Hossain, T. Sato, U. Rana, S. Moriyama, M. Higuchi,
RSC Adv., 5, 49224-49230 (2015).
10.1039/c5ra07217d

Proton Conduction in Mo(VI)-Based Metallo-Supramolecular Polymers,
R. K. Pandey, M. D. Hossain, C. Chakraborty, S. Moriyama, M. Higuchi,
Chem. Commun., 51, 11012-11014 (2015). (Selected to back cover)
10.1039/c5cc03634h

Synthesis of Metallo-Supramolecular Polymers with Bis-NNN-Tridentate Ligand for Electrochromic Devices,
M. Kanao, M. Higuchi,
J. Photopolym. Sci. Technol., 28, 363-368 (2015).
10.2494/photopolymer.28.363

Nano Molar Detection of Cd(II) Ions by Luminescent Metallo-Supramolecular Polymer Formation,
M. D. Hossain, R. K. Pandey, U. Rana, M. Higuchi,
J. Mater. Chem. C, 3, 12186-12191 (2015). (Selected to back cover)
10.1039/c5tc02734a

Black-to-Transmissive Electrochromism with Visible-to-Near-Infrared Switching of a Co(II)-Based Metallo-Supramolecular Polymer for Smart Window and Digital Signage Applications,
C.-Y. Hsu, J. Zhang, T. Sato, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 7, 18266-18272 (2015).
10.1021/acsami.5b02990
[The most cited paper of the year]
[One of the most cited papers]

Platinum(II)-Based Metallo-Supramolecular Polymer with Controlled Unidirectional Dipoles for Tunable Rectification,
C. Chakraborty, R. K. Pandey, M. D. Hossain, Z. Futera, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 7, 19034-19042 (2015).
10.1021/acsami.5b03434

Printed Multi-Color High-Contrast Electrochromic Devices,
B.-H. Chen, S.-Y. Kao, C.-W. Hu, M. Higuchi, K.-C. Ho, Y.-C. Liao,
ACS Appl. Mater. Interfaces, 7, 25069-25076 (2015).
10.1021/acsami.5b08061
[One of the most cited papers]

Articles in 2014
Real-Time Humidity-Sensing Properties of Ionically Conductive Ni(II)-Based Metallo-Supramolecular Polymers,
R. K. Pandey, M. D. Hossain, S. Moriyama, M. Higuchi,
J. Mater. Chem. A, 2, 7618-7618 (2014). (Selected to inside front cover)
10.1039/c4ta00884g

Anion Effects to Electrochromic Properties of Ru-based Metallo-Supramolecular Polymers,
J. Zhang, C.-Y. Hsu, M. Higuchi,
J. Photopolym. Sci. Technol., 27, 297-300 (2014).
10.2494/photopolymer.27.297

メタロ超分子ポリマーの分子設計と電子・光機能
Design of Metallo-Supramolecular Polymers with Electronic and Optical Properties,
M. Higuchi,
高分子論文集, 71, 624-629 (2014).
10.1295/koron.71.624

Selective Edge Modification in Graphene and Graphite by Chemical Oxidation,
M. Yang, S. Moriyama, M. Higuchi,
J. Nanosci. Nanotechnol., 14, 2974-2978 (2014).
10.1166/jnn.2014.8578

Three-Dimensional Fe(II)-Based Metallo-Supramolecular Polymers with Electrochromic Properties of Quick Switching, Large Contrast, and High Coloration Efficiency,
C.-W. Hu, T. Sato, J. Zhang, S. Moriyama, M. Higuchi,
ACS Appl. Mater. Interfaces, 6, 9118-9125 (2014).
10.1021/am5010859
[One of the most cited papers]

Synthesis of Metallo-Supramolecular Polymers with a Bis-ONO-tridentate Ligand by Coordination Programming,
M. Kanao, M. Higuchi,
Chem. Lett., 43, 1075-1077 (2014).
10.1246/cl.140253

A Heterometallo-Supramolecular Polymer with CuI and FeII Ions Introduced Alternately,
M. D. Hossain, J. Zhang, R. K. Pandey, T. Sato, M. Higuchi,
Eur. J. Inorg. Chem., 2014, 3763-3770 (2014).
10.1002/ejic.201402468

Stimuli-Responsive Metallo-Supramolecular Polymer Films: Design, Synthesis and Device Fabrication,
M. Higuchi,
J. Mater. Chem. C, 2, 9331-9341 (2014) (Feature article). (Selected to outside back cover)
10.1039/c4tc00689e
[The most cited paper of the year]
[One of the most cited papers]

Articles in 2013
Metallo-Supramolecular Polymers: Versatile DNA Binding and Their Cytotoxicity,
J. Li, T. Murakami, M. Higuchi,
J. Inorg. Organomet. Polym. Mater., 23, 119-125 (2013).
10.1007/s10904-012-9752-2

A Green Color Copper-Based Metallo-Supramolecular Polymer: Synthesis, Structure, and Electrochromic Properties,
Md. Delwar Hossain, T. Sato, M. Higuchi,
Chem. Asian J., 8, 76-79 (2013).
10.1002/asia.201200668
[One of the most cited papers]

Multi-Colour Electrochromic Properties of Fe/Ru-Based Bimetallo-Supramolecular Polymers,
C.-W. Hu, T. Sato, J. Zhang, S. Moriyama, M. Higuchi,
J. Mater. Chem. C, 1, 3408-3413 (2013). (Selected to back cover)
10.1039/c3tc30440j
[The most cited paper of the year]
[One of the most cited papers]

An Alternately Introduced Heterometallo-Supramolecular Polymer: Synthesis and Solid-State Emission Switching by Electrochemical Redox,
T. Sato, M. Higuchi,
Chem. Commun., 49, 5256-5258 (2013). (Selected to back cover)
10.1039/c3cc41176a
[One of the most cited papers]

Ionic Conductivity of Ni(II)-Based Metallo-Supramolecular Polymers: Effects of Ligand Modification,
R. K. Pandey, M. D. Hossain, S. Moriyama, M. Higuchi,
J. Mater. Chem. A, 1, 9016-9018 (2013). (Selected to outside front cover)
10.1039/c3ta12080e

Fluorescent Colour Modulation in Zn(II)-Based Metallo-Supramolecular Polymer Films by Electronic-State Control of the Ligand,
T. Sato, R. K. Pandey, M. Higuchi,
Dalton Trans., 42, 16036-16042 (2013).
10.1039/c3dt51354h

Synthesis of Metallo-Supramolecular Polymers Using 5,5'-Linked Bis(1,10-Phenanthroline) Ligands,
M. D. Hossain, M. Higuchi,
Synthesis, 45, 753-758 (2013).
10.1055/s-0032-1316858

From Metal Complexes to Metallosupramolecular Polymers via Polycondensation: Synthesis, Structure and Electrochromic Properties of Co(III)- and Fe(III)-Based Metallosupramolecular Polymers with Aromatic Azo Ligands,
A. Bandyopadhyay, M. Higuchi,
Eur. Polym. J., 49, 1688-1697 (2013).
10.1016/j.eurpolymj.2013.03.015

Electrochemical Switching of Luminescence in a Ru(II)-Based Metallo-Supramolecular Polymer Device,
Y. Muronoi, J. Zhang, M. Higuchi, H. Maki,
Chem. Lett., 42, 761-763 (2013).
10.1246/cl.130158

Articles in 2012
Chiral Phenylazomethine Cage,
R. Shomura, S. Higashibayashi, H. Sakurai, Y. Matsushita, A. Sato, M. Higuchi,
Tetrahedron Lett., 53(7), 783-785 (2012).
10.1016/j.tetlet.2011.11.141

A Vapoluminescent Eu-Based Metallo-Supramolecular Polymer,
T. Sato, M. Higuchi,
Chem. Commun., 48(41), 4947-4949 (2012). (Selected to back cover)
10.1039/c2cc30972f
[The most cited paper of the year]
[One of the most cited papers]

Articles in 2011
Aromatic Macrocycle Containing Amine and Imine Groups: Intramolecular Charge-Transfer and Multiple Redox Behavior,
T. Ide, D. Takeuchi, K. Osakada, T. Sato, M. Higuchi,
J. Org. Chem., 76(22), 9504-9506 (2011).
10.1021/jo201650t

Gold Nanoparticles with Cyclic Phenylazomethines: One-pot Synthesis and Metal-Ion Sensing,
R. Shomura, K. J. Chung, H. Iwai, M. Higuchi,
Langmiur, 27(13), 7972-7975 (2011).
10.1021/la201067q

Synthesis of Unsymmetrical, Mono-substituted Bis-terpyridine Derivatives via Suzuki-Miyaura Cross-Coupling,
J. Li, T. Sato, H. Li, M. Higuchi,
Synthesis, 2011(9), 1361-1364 (2011).
10.1055/s-0030-1259986

Conjugation of Organic-Metallic Hybrid Polymers and Calf-Thymus DNA,
J. Li, Z. Futera, H. Li, Y. Tateyama, M. Higuchi,
Phys. Chem. Chem. Phys., 13(11), 4839-4841 (2011).
10.1039/c0cp02037k

Tuning of Nonvolatile Bipolar Memristive Switching in Co(III) Polymer with an Extended Azo Aromatic Ligand,
A. Bandyopadhyay, S. Sahu, M. Higuchi,
J. Am. Chem. Soc., 133(5), 1168-1171 (2011).
10.1021/ja106945v
[The most cited paper of the year]
[One of the most cited papers]

Synthesis of Thiophene-Capped [2]Rotaxanes,
T. Ikeda, M. Higuchi,
Tetrahedron, 67(17), 3046-3052 (2011).
10.1016/j.tet.2011.03.009

Electrochromic Properties of Polythiophene Polyrotaxane Film,
T. Ikeda, M. Higuchi,
Langmiur, 27(7), 4184-4189 (2011).
10.1021/la1043816
エレクトロクロミック機能を有する有機／金属ハイブリッドポリマーの開発と表示デバイスへの応用,
M. Higuchi,
有機合成化学協会誌, 69(3), 229-235 (2011).
10.5059/yukigoseikyokaishi.69.229

Articles in 2010
Substituent Effects on Metallo-Supramolecular Coordination Polymers,
J. Li, M. Higuchi,
J. Inorg. Organomet. Polym. Mater., 20, 10-18 (2010).
10.1007/s10904-010-9331-3
[The most cited paper of the year]

Fluorescent Fe(II) Metallo-Supramolecular Polymers: Metal-Ion-Directed Self-Assembly of New Bisterpyridines Containing Triethylene Glycol Chains,
R. R. Pal, M. Higuchi, Y. Negishi, T. Tsukuda, D. G. Kurth,
Polym. J., 42, 336-341 (2010).
10.1038/pj.2010.3

有機/金属ハイブリッドポリマーにおける構造制御と電子・光機能制御,
M. Higuchi,
高分子論文集, 67(7), 368-374 (2010).
10.1295/koron.67.368

Articles in 2009
Optically Active Metallo-Supramolecular Polymers Derived from Chiral Bis-terpyridines,
R. R. Pal, M. Higuchi, D. G. Kurth,
Org. Lett., 11(16), 3562-3565 (2009).
10.1021/ol901293r

Electrochromic Functions of Organic-Metallic Hybrid Polymers,
M. Higuchi,
J. Nanosci. Nanotechnol., 9(1), 51-58 (2009).
10.1166/jnn.2009.J034

Formation of (FeCl3)@phenylazomethine Dendrimer (DPA): Fine Control of the Release and Encapsulation of Fe Ions in Dendrimers,
K. Yamamoto, R. Nakajima, Y. Ochi, M. Tsuruta, M. Higuchi, A. Hida, J. Onoe,
Pure Appl. Chem., 81(12), 2253-2263 (2009).
10.1351/PAC-CON-09-01-13

Inclusion Complexation of Cyclobis(paraquat-p-phenylene) with Thiophene, Bithiophene and Terthiophene,
T. Ikeda, M. Higuchi, D. G. Kurth,
J. Incl. Phenom. Macrocycl. Chem., 64, 299-303 (2009).
10.1007/s10847-009-9566-1

From Thiophene [2]Rotaxane To Polythiophene Polyrotaxane,
T. Ikeda, M. Higuchi, D. G. Kurth,
J. Am. Chem. Soc., 131(26), 9158-9159 (2009).
10.1021/ja902992c
[One of the most cited papers]

Electrochromic Solid-State Devices Using Organic-Metallic Hybrid Polymers,
M. Higuchi, Y. Akasaka, T. Ikeda, A. Hayashi, D. G. Kurth,
J. Inorg. Organomet. Polym. Mater., 19, 74-78 (2009).
10.1007/s10904-008-9243-7
[One of the most cited papers]

Electrochromic Organic–Metallic Hybrid Polymers: Fundamentals and Device Applications,
M. Higuchi,
Polym. J., 41, 511-520 (2009).
10.1295/polymj.PJ2009053
[The most cited paper of the year]
[One of the most cited papers]

beta-Substituted Terthiophene [2]Rotaxanes,
T. Ikeda, M. Higuchi, D. G. Kurth,
Chem. Eur. J., 15(19), 4906-4913 (2009).
10.1002/chem.200802120

Articles in 2008
Synthesis of pai-Conjugated Pyridine Ring Functionalized Bis-terpyridines with Efficient Green, Blue and Purple Emission,
F. Han, M. Higuchi, D. G. Kurth,
Tetraherdon, 64(38), 9108-9116 (2008).
10.1016/j.tet.2008.06.106

Synthesis of Tetrathiafulvalene-Functionalized Organic-Metal Hybrid Polymer,
T. Ikeda, M. Higuchi, D. G. Kurth,
Trans. Mater. Res. Soc. J., 33(2), 403-405 (2008).
10.14723/tmrsj.33.403

Syntheses of Novel Bis-terpyridine and Cyclic Phenylazomethine as Organic Modules in Organic-Metallic Hybrid Materials,
M. Higuchi, Y. Otsuka, R. Shomura, D. G. Kurth,
Thin Solid Films, 516(9), 2416-2420 (2008).
10.1016/j.tsf.2007.04.107

Preparation, Characterization, and Electrochromic Properties of Novel Co(II)-bis-2,2’:6’,2”-terpyridine Metallo-Supramolecular Polymers,
F. Han, M. Higuchi, Y. Akasaka, Y. Ohtsuka, D. G. Kurth,
Thin Solid Films, 516(9), 2469-2473 (2008).
10.1016/j.tsf.2007.04.144

Metallo-Supramolecular Polyelectrolytes Self-assembled from Various Pyridine Ring Substituted Bis-terpyridines and Metal Ions: Photophysical, Electrochemical and Electrochromic Properties,
F. Han, M. Higuchi, D. G. Kurth,
J. Am. Chem. Soc., 130(6), 2073-2081 (2008).
10.1021/ja710380a
[The most cited paper of the year]
[One of the most cited papers]

Thiophene Donor-Acceptor [2]Rotaxanes,
T. Ikeda, M. Higuchi, A. Sato, D. G. Kurth,
Org. Lett., 10(11), 2215-2218 (2008).
10.1021/ol800624c

Luminescence Properties of Metallo-Supramolecular Coordination Polymers Assembled from Pyridine Ring Functionalized Ditopic Bis-terpyridines and Ru(II) Ion,
F. Han, M. Higuchi, T. Ikeda, Y. Negishi, T. Tsukuda, D. G. Kurth,
J. Mater. Chem., 18(38), 4555-4560 (2008).
10.1039/b806930a
[One of the most cited papers]

有機/金属ハイブリッドポリマーの創製とエレクトロクロミック機能,
M. Higuchi,
高分子論文集, 65(6), 399-404 (2008).
10.1295/koron.65.399

Articles in 2007
Metallo-Supramolecular Polymers Based on Functionalized Bis-terpyridines as Novel Electrochromic Materials,
F. Han, M. Higuchi, D. G. Kurth,
Adv. Mater., 19(22), 3928-3931 (2007).
10.1002/adma.200700931
[The most cited paper of the year]
[One of the most cited papers]

Heterometal Assembly in Dendritic Polyphenylazomethines,
K. Takanashi, A. Fujii, R. Nakajima, H. Chiba, M. Higuchi, Y. Einaga, K. Yamamoto,
Bull. Chem. Soc. Jpn, 80(8), 1563-1572 (2007).
10.1246/bcsj.80.1563
[One of the most cited papers]

Diverse Synthesis of Novel Bisterpyridines via Suzuki-Type Cross-Coupling,
F. Han, M. Higuchi, D. G. Kurth,
Org. Lett., 9(4), 559-562 (2007).
10.1021/ol062788h
[One of the most cited papers]

Synthesis of Organic-Metallic Hybrid Polymers Using Novel Bis-terpyridines Bearing Alkoxy Chains,
M. Higuchi, Y. Ohtsuka, Y. Akasaka, D. G. Kurth,
Trans. Mater. Res. Soc. J., 32(3), 759-762 (2007).
10.14723/tmrsj.32.763

Preferential Synthesis of Cyclic Pheylazomethines and Their Redox Behavior,
R. Shomura, M. Higuchi, D. G. Kurth,
Trans. Mater. Res. Soc. J., 32(3), 763-766 (2007).
10.14723/tmrsj.32.759

Synthesis of Novel Bis(terpyridyl)benzene Derivatives as Organic Modules in Organic-Metallic Hybrid Polymers,
M. Higuchi, Y. Ohtsuka, D. G. Kurth,
Trans. Mater. Res. Soc. J., 32(2), 425-428 (2007).
10.14723/tmrsj.32.425

Electrochemical Functions of Metallo-Supramolecular Nano-Materials,
M. Higuchi, D. G. Kurth,
Chem. Rec., 7(4), 203-209 (2007).
10.1002/tcr.20118
[One of the most cited papers]

Articles in 2006
Synthesis of DPA Dendron Encapsulated Gold Clusters with Metal-Assembling Function,
Y. Men, M. Higuchi, K. Yamamoto,
Sci. Tech. Adv. Mater., 7, 139-144 (2006).
10.1016/j.stam.2005.10.007

Sequential Metal Ion Assembly in Cyclic Phenylazomethine,
M. Higuchi, R. Shomura, Y. Ohtsuka, A. Hayashi, K. Yamamoto, D. G. Kurth,
Org. Lett., 8(21), 4723-4726 (2006).
10.1021/ol061758b

The Solid-State Architecture of a Metallo-Supramolecular Polyelectrolyte,
U. Kolb, K. Buscher, C. A. Helm, A. Lindner, A. F. Thunemann, M. Menzel, M. Higuchi, D. G. Kurth,
Proc. Natl. Acad. Sci. USA, 103(27), 10202-10206 (2006).
10.1073/pnas.0601092103
[One of the most cited papers]

Metal Ion Assembly in Macromolecules,
M. Higuchi, A. Hayashi, D. G. Kurth,
J. Nanosci. Nanotechnol., 6(6), 1533-1551 (2006).
10.1166/jnn.2006.250

Modification and Electrochemical Properties of Poly(phenylazomethine) Derivatives,
M. Higuchi, A. Hayashi, K. Yamamoto,
Macromol. Symposia, 235(1), 121-126 (2006).
10.1002/masy.200650315

Functional Modules: Metal Ion Assembly in Novel Topological Poly(phenylazomethine)s,
M. Higuchi, D. G. Kurth, K. Yamamoto,
Thin Solid Films, 499(1-2), 234-241 (2006).
10.1016/j.tsf.2005.07.043

Synthesis of Ferrocene-Modified Phenylazomethine Dendrimers Possessing Redox Switching,
M. Suzuki, R. Nakajima, M. Tsuruta, M. Higuchi, Y. Einaga, K. Yamamoto,
Macromolecules, 39(1), 64-69 (2006).
10.1021/ma052268m

Synthesis and Chemical Degradation of Thermostable Polyamide with Imine Bond for Chemical Recycling,
H. Kanazawa, M. Higuchi, K. Yamamoto,
Macromolecules, 39(1), 138-144 (2006).
10.1021/ma0520141

Transition Metal Ions: Weak Links for Strong Polymers,
D. G. Kurth, M. Higuchi,
Soft Matter, 2(11), 915-927 (2006).
10.1039/B607485E
[The most cited paper of the year]
[One of the most cited papers]

Articles in 2005
An Electric Cyclophane: Cavity Control Based on the Rotation of a Paraphenylene by Redox Switching,
H. Kanazawa, M. Higuchi, K. Yamamoto,
J. Am. Chem. Soc., 127(47), 16404-16405 (2005).
10.1021/ja055681i
[The most cited paper of the year]
[One of the most cited papers]

Phenylazomethine Dendrimer Complexes as Novel Hole-Transporting Materials of Organic Light-Emitting Diodes,
J.-S. Cho, K. Takanashi, M. Higuchi, K. Yamamoto,
Synth. Met., 150(1), 79-82 (2005).
10.1016/j.synthmet.2005.01.019
[One of the most cited papers]

Synthesis of Diphenylamine-Substituted Phenylazomethine Dendrimers and the Performance of Organic Light-Emitting Diodes,
J.-S. Cho, A. Kimoto, M. Higuchi, K. Yamamoto,
Macromol. Chem. Phys., 206(6), 635-641 (2005).
10.1002/macp.200400381

Novel Functional Groups with Fine-Controlled Metal Assembling Function,
K. Yamamoto, M. Higuchi, A. Kimoto, T. Imaoka, K. Masachika,
Bull. Chem. Soc. Jpn, 78(2), 349-355 (2005).
10.1246/bcsj.78.349

Fine-Control of Metal Ion Assembly in Novel Topological Poly(phenylazomethine)s,
M. Higuchi, K. Yamamoto,
Trans. Mater. Res. Soc. J., 30(3), 623-626 (2005).

Triarylamine Dendrimers with a Controlled Metal-Assembling Function for Organic EL Devices,
N. Satoh, J.-S. Cho, M. Higuchi, K. Yamamoto,
J. Photopolym. Sci. Technol., 18(1), 55-58 (2005).
10.2494/photopolymer.18.55

A High Energy Rechargeable Battery Based on a One-step Successive Two-electron Transfer Process,
K. Nishi, T. Nishiumi, M. Higuchi, K. Yamamoto,
Electrochem. Solid State Lett., 8(8), A382-A384 (2005).
10.1149/1.1940490

Articles in 2004
Synthesis and Electroluminescence Properties of Novel Main Chain Poly(p-phenylenevinylene)s Possessing Pendant Phenylazomethine Dendrons as Metal Ligation Sites,
A. Kimoto, K. Masachika, J.-S. Cho, M. Higuchi, K. Yamamoto,
Chem. Mater., 16(26), 5706-5712 (2004).
10.1021/cm049241m

Fine-Control of Metal Assembling in Dendritic Polyphenylazomethines,
K. Yamamoto, M. Higuchi,
Polym. J., 36(8), 577-586 (2004).
10.1295/polymj.36.577

Synthesis of Asymmetrically Arranged Dendrimers with a Carbazole Dendron and a Phenylazomethine Dendron,
A. Kimoto, J.-S. Cho, M. Higuchi, K. Yamamoto,
Macromolecules, 37(15), 5531-5537 (2004).
10.1021/ma0499674
[The most cited paper of the year]
[One of the most cited papers]

The Class II/III Transition Electron Transfer on an Infrared Vibrational Time Scale for N,N'-Diphenyl-1,4-phenylenediamine Structures,
T. Nishiumi, Y. Nomura, Y. Chimoto, M. Higuchi, K. Yamamoto,
J. Phys. Chem. B, 108(23), 7992-8000 (2004).
10.1021/jp0492265

Novel pai-Conjugated Nano-Supramolecules Having Precise Metal-Assembling Function,
M. Higuchi, K. Yamamoto,
Bull. Chem. Soc. Jpn, 77(5), 853-874 (2004). (Award Accounts)
10.1246/bcsj.77.853

Efficient Synthesis of Poly(phenylazomethine) Dendrons Allowing Access to Higher Generation Dendrimers,
K. Takanashi, H. Chiba, M. Higuchi, K. Yamamoto,
Org. Lett., 6(11), 1709-1712 (2004).
10.1021/ol049656d
[One of the most cited papers]

Novel Poly(p-phenylenevinylene)s with a Phenylazomethine Dendron as a Metal-Collecting Site,
A. Kimoto, K. Masachika, J.-S. Cho, M. Higuchi, K. Yamamoto,
Org. Lett., 6(7), 1179-1182 (2004).
10.1021/ol0497741

First Redox Polymer Bearing One-Step Successive Two-Electron-Transfer Process Based on Redox Potential Inversion,
T. Nishiumi, Y. Chimoto, Y. Hagiwara, M. Higuchi, K. Yamamoto,
Macromolecules, 37(7), 2661-2664 (2004).
10.1021/ma035370x

Novel Carbazole Dendrimers Having a Metal Coordination Site as a Unique Hole-Transport Material,
A. Kimoto, J.-S. Cho, M. Higuchi, K. Yamamoto,
Macromol. Symposia, 209(1), 51-65 (2004).
10.1002/masy.200450504

Fine Control of the Release and Encapsulation of Fe Ions in Dendrimers Through Ferritin-Like Redox Switching,
R. Nakajima, M. Tsuruta, M. Higuchi, K. Yamamoto,
J. Am. Chem. Soc., 126(6), 1630-1631 (2004).
10.1021/ja037480p
[One of the most cited papers]

Fluorescence Switching Based on the Redox Reaction of Quinones Induced by Complexation with Rare-Earth Metals,
T. Kamimura, T. Nishiumi, M. Higuchi, K. Yamamoto,
Electrochem. Solid-State Lett., 7(2), H9-H11 (2004).
10.1149/1.1637562

Dendritic Polyphenylazomethines: Synthesis, Structures, and Metal-Assembling Functions,
K. Yamamoto, M. Higuchi,
Pure Appl. Chem., 76(7-8), 1399-1408 (2004).
10.1351/pac200476071399

精密金属集積高分子材料の創製と応用,
K. Yamamoto, M. Higuchi,
有機合成化学協会誌, 62(5), 433-439 (2004).
10.5059/yukigoseikyokaishi.62.433

Articles in 2003
Intra-Molecular Energy Transfer Characteristics of Novel Oligo(thienylphenyl)amine Derivatives Having a Gradient Structure,
J. -S. Cho, Y. Kojima, N. Sato, M. Higuchi, K. Yamamoto,
Macromol. Chem. Phys., 204(18), 2175-2182 (2003).
10.1002/macp.200350078

Control of Stepwise Radial Complexation in Dendritic Polyphenylazomethines,
M. Higuchi, M. Tsuruta, H. Chiba, S. Shiki, K. Yamamoto,
J. Am. Chem. Soc., 125(33), 9988-9997 (2003).
10.1021/ja035608x
[One of the most cited papers]

Synthesis of Novel Carbazole Dendrimers Having a Metal Coordination Site,
A. Kimoto, J-S Cho, M. Higuchi, K. Yamamoto,
Chem. Lett., 32(8), 674-675 (2003).
10.1246/cl.2003.674

pai-Conjugated Polymers Exhibiting a Novel Doping Based on Redox of Side Chains,
T. Nishiumi, M. Higuchi, K. Yamamoto,
Macromolecules, 36(17), 6325-6332 (2003).
10.1021/ma025833j

Electron Transfer Rate on Mixed Valence States of Class II/III Transition for N,N'-Diphenyl-1,4-phenylenediamine Structures as a Polyaniline Unit,
T. Nishiumi, Y. Nomura, M. Higuchi, K. Yamamoto,
Chem. Phys. Lett., 378(1-2), 18-23 (2003).
10.1016/S0009-2614(03)01237-5

Novel Triarylamine Dendrimers as a Hole-transport Material with Controlled Metal-Assembling Function,
N. Satoh, J. -S. Cho, M. Higuchi, K. Yamamoto,
J. Am. Chem. Soc., 125(27), 8104-8105 (2003).
10.1021/ja034811p
[The most cited paper of the year]
[One of the most cited papers]

The First Electroresponsive Phenylazomethine Macrocycles: Highly Preferential Formation and Regular Molecular Packing,
M. Higuchi, H. Kanazawa, K. Yamamoto,
Org. Lett., 5(3), 345-347 (2003).
10.1021/ol0273755

Articles in 2002
Stoichiometric Complexes between Cyclic Phenylazomethines and a Dialkyl Phosphate for Molecular Tiling at the Air-Water Interface,
K. Ariga, R. Tanaka, J. Kikuchi, M. Higuchi, K. Yamamoto,
J. Nanosci. Nanotechnol., 2(6), 669-674 (2002).
10.1166/jnn.2002.147

Oligophenylazomethines: Synthesis, Structure, Electrochemical Property and Photo-cyclization,
M. Higuchi, K. Yamamoto,
Polym. Adv. Technol., 13(10-12), 765-770 (2002).
10.1002/pat.255

Novel pai-Conjugated Polymers Exhibiting Conductive-Insulator Transition Based on the Redox of PDA Units through Electron Communication,
T. Nishiumi, M. Higuchi, K. Yamamoto,
Electrochem., 70(9), 668-670 (2002).
10.5796/electrochemistry.70.668

A Novel Synthetic Route of Redox-active Oligo(thio-1,4-phenylene) Derivatives via a Michael-type Addition,
K. Yamamoto, M. Higuchi, T. Nishiumi, H. Takai,
Bull. Chem. Soc. Jpn, 75(8), 1827-1832 (2002).
10.1246/bcsj.75.1827

Synthesis and Electrochemical Properties of Oligo- and Poly(thienylphenylamine)s,
K. Yamamoto, M. Higuchi, K. Uchida, Y. Kojima,
Macromolecules, 35(15), 5782-5788 (2002).
10.1021/ma011018c

Novel Linear and Hyperbranched Aromatic Polyamide with Phenylazomethine Units for Chemical Recycling,
K. Yamamoto, M. Higuchi, H. Kanazawa,
Chem. Lett., 31(7), 692-693 (2002).
10.1246/cl.2002.692

Stepwise Radial Complexation of Imine Groups in Phenylazomethine Dendrimers,
K. Yamamoto, M. Higuchi, S. Shiki, M. Tsuruta, H. Chiba,
Nature, 415, 509-511 (2002).
10.1038/415509a
[The most cited paper of the year]
[One of the most cited papers]

精密金属集積能を有するポリフェニルアゾメチン新ナノ構造体,
M. Higuchi, K. Yamamoto,
有機合成化学協会誌, 60(9), 869-877 (2002).
10.5059/yukigoseikyokaishi.60.869

Articles in 2001
Controlled Cyclotrimerization in Hyperbranched Polymer Synthesis,
M. Higuchi, H. Kanazawa, M. Tsuruta, K. Yamamoto,
Macromolecules, 34(26), 8847-8850 (2001).
10.1021/ma0111461

First Synthesis of Phenylazomethine Dendrimer Ligands and Structural Studies,
M. Higuchi, S. Shiki, K. Ariga, K. Yamamoto,
J. Am. Chem. Soc., 123(19), 4414-4420 (2001).
10.1021/ja004239r
[The most cited paper of the year]
[One of the most cited papers]

Novel Synthesis of Electroresponsive Poly(thiophenylene) through a Michael-Type Addition,
K. Yamamoto, M. Higuchi, H. Takai, T. Nishiumi,
Org. Lett., 3(1), 131-134 (2001).
10.1021/ol0068501

Excellent Redox Properties of Poly(thienylphenylamine)s,
K. Yamamoto, M. Higuchi, K. Uchida, Y. Kojima,
Macromol. Rapid. Commun., 22(4), 266-270 (2001).
10.1002/1521-3927(20010201)22:4<266::AID-MARC266>3.0.CO;2-8

Articles in 2000
Novel Phenylazomethine Dendrimers: Synthesis and Structural Properties,
M. Higuchi, S. Shiki, K. Yamamoto,
Org. Lett., 2(20), 3079-3082 (2000).
10.1021/ol006241t
[The most cited paper of the year]
[One of the most cited papers]

Selective Synthesis of Novel Cyclic Phenylazomethine Trimers,
M. Higuchi, A. Kimoto, S. Shiki, K. Yamamoto,
J. Org. Chem., 65(18), 5680-5684 (2000).
10.1021/jo000509c
[One of the most cited papers]

Articles in 1999
Novel Cyclic Molecules: Selective Synthesis of Cyclic Phenylazomethines,
M. Higuchi, K. Yamamoto,
Org. Lett., 1(12), 1881-1883 (1999).
10.1021/ol990975s
[The most cited paper of the year]
[One of the most cited papers]

Articles in 1998
A Novel Redox System Consisting of pai-Conjugated Polymers and Transition Metals,
T. Hirao, M. Higuchi, S. Yamaguchi,
Macromol. Symposia, 131(1), 59-68 (1998).
10.1002/masy.19981310109
[The most cited paper of the year]

Articles in 1997 (D3)
A Novel Synthetic Metal Catalytic System,
M. Higuchi, I. Ikeda, T. Hirao,
J. Org. Chem., 62(4), 1072-1078 (1997).
10.1021/jo9617575
[The most cited paper of the year]
[One of the most cited papers]

合成金属触媒システムの構築と特性,
M. Higuchi, T. Hirao,
高分子論文集, 54(10), 632-640 (1997).
10.1295/koron.54.632

Articles in 1996 (D2)
Construction of Palladium-Polypyrrole Catalytic System in the Wacker Oxidation,
M. Higuchi, S. Yamaguchi, T. Hirao,
Synlett, 1996(12), 1213-1214 (1996).
10.1055/s-1996-5722
[One of the most cited papers]

Redox Behavior of Polyaniline-Transition Metal Complexes in Solution,
M. Higuchi, D. Imoda, T. Hirao,
Macromolecules, 29(25), 8277-8279 (1996).
10.1021/ma960761f
[The most cited paper of the year]
[One of the most cited papers]

Articles in 1995 (D1)
A Novel Redox System for the Palladium(II)-Catalyzed Oxidation Based on Redox of Polyanilines,
T. Hirao, M. Higuchi, B. Hatano, I. Ikeda,
Tetrahedron Lett., 36(33), 5925-5928 (1995).
10.1016/0040-4039(95)01143-6
[The most cited paper of the year]
[One of the most cited papers]

Articles in 1993 (M1)
Doping Effect of Polyaniline Derivatives on Synthetic Metal Catalytic System for Dehydrogenative Oxidation of Benzylamine,
T. Hirao, M. Higuchi, Y. Ohshiro, I. Ikeda,
Chem. Lett., 22(11), 1889-1890 (1993).
10.1246/cl.1993.1889

A Novel Synthetic Metal Catalytic System for Dehydrogenative Oxidation Based on Redox of Polyaniline,
T. Hirao, M. Higuchi, I. Ikeda, Y. Ohshiro,
J. Chem. Soc., Chem. Commun., 1993(2), 194-195 (1993).
10.1039/C39930000194
[The most cited paper of the year]
[One of the most cited papers]

Contact

Dr. Masayoshi HIGUCHI / 樋口昌芳
Tel: +81-29-860-4721
E-mail: HIGUCHI.Masayoshi(delete here)@nims.go.jp