Nanomaterials Field
Supermolecules Group

We will develop innovative materials that are unprecedented in the world from molecule to practical applications upon supramolecular chemistry.

Group Leader: Katsuhiko Ariga

A novel material: MOFOF

Current Topics

The main results show that the novel synthesis and characterisation of MOFOF composites demonstrate the successful integration of coordination and supramolecular chemistry for the design and fabrication of advanced hierarchical composites with tailored properties, including micro- and mesopore channels, interfacial facets and defect sites. These properties are expected to lead to numerous potential applications such as gas storage and separation, catalysis, sensing, energy storage and environmental remediation.
Fig. 1. Metal-organic framework on fullerene (MOFOF) as a hierarchical composite by the integration of coordination chemistry and supramolecular chemistry

Outline of Research

We have invented a novel approach for the synthesis and characterization of metal-organic framework on supramolecular fullerene (MOFOF) composites [1], achieved through the integration of coordination chemistry and supramolecular chemistry principles. The two-step synthesis procedure involves the controlled assembly of fullerenes as tubular nanostructures (fullerene nanotubes), their surface functionalization and the on-surface growth of MOF (in this case ZIF-67).

References

  1. B. N. Bhadra, L. K. Shrestha, R. Ma, J. P. Hill, Y. Yamauchi, K. Ariga, ACS Appli. Mater. Interfaces 16, 41363 (2024). DOI: 10.1021/acsami.4c09747

Group members

  • Profile image
    Katsuhiko Ariga
    ・Group Leader
    ・Senior Scientist with Special Missions
  • Profile image
    Junichi Takeya
    ・Invited Researcher
  • Profile image
    Yusuke Yamauchi
    ・Satellite Principal Investigator
    ・Chief Invited Researcher
  • Profile image
    Lok Kumar Shrestha
    ・Principal Researcher
  • Profile image
    Yu Yamashita
    ・Senior Researcher

Activities

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