Nanomaterials Field
Layered Nanochemistry Group

Development of synthetic/functionalization methods for layered materials like clay minerals and related low-dimensional nanomaterials

Group Leader: Yusuke Ide

1 nm-thick ultra-thin titanate nanowires showing an excellent cation exchange performance exceeding existing cation exchangers

Current Topics

Demand on high-performance ion exchangers is ever-increasing in energy and environment applications. Among many cation exchangers, layered alkali titanates generally show larger cation exchange capacity, but slower cation exchange rate due to their 2D micrometer-size particle morphologies, which limits their practical applications. We report a rational conversion of a layered sodium titanate, Na₂Ti₃O₇, to the corresponding 1D, 1 nm-thick nanowires via hydrothermal treatment under a specific basic condition [4]. The formation of nanowires is thought to involve the partial exfoliation of Na₂Ti₃O₇ to form thin plate-like particles that subsequently split into nanowires along a crystallographically defined, chemically selective weakness in the Na₂Ti₃O₇ crystals (Fig. 1). The cation exchange rate and amount of Na₂Ti₃O₇ nanowire was much faster and higher, respectively, than those of existing cation exchangers such as zeolites and organic resins.
Fig. 1. Schematic drawing for 2D-to-1D conversion of Na₂Ti₃O₇.

Outline of Research

We are aiming at the development of high-performance, cost-effective, and environmentally friendly materials alternative to existing commodities and industrial products including ion exchangers/adsorbents, sunscreen/cosmetic products, and catalysts. [1-4]

References

  1. E. Doustkhah et al., ACS Appl. Mater. Interfaces 16, 10251 (2024). DOI: 10.1021/acsami.3c18709
  2. M. Esmat et al., ACS Appl. Mater. Interfaces 16, 51046 (2024). DOI: 10.1021/acsami.4c08845
  3. E. Doustkhah et al., ACS Appl. Mater. Interfaces 16, 64736 (2024). DOI: 10.1021/acsami.4c13770
  4. E. Moustafa et al., Small Methods 2400947 (2024). DOI: 10.1002/smtd.202400947

Group members

  • Yusuke Ide
    Yusuke Ide
    ・Group Leader
  • Mitsutake Oshikiri
    Mitsutake Oshikiri
    ・Principal Researcher
  • Watcharop Chaikittisilp
    Watcharop Chaikittisilp
    ・Senior Researcher

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