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Poster QM-06

Probing Chalcogen Vacancy Defects in Transition Metal Dichalcogenides Using Photocurrent Spectroscopy

Srest Somay

Author

Srest Somay and Ryo Kitaura

Affiliation

2D Quantum Materials Group, MANA, NIMS

URL

https://www.nims.go.jp/group/lowDmaterials/index.html

Biography

Srest Somay is pursuing a PhD at the Indian Institute of Technology Delhi and is currently working at NIMS as part of the LOTUS program. His research interest lies in defect control and characterization in low-dimensional materials.

Abstract

Defects in transition-metal dichalcogenides (TMDs) hinder the realization of high-performance devices, making controlled growth strategies that reduce defect densities essential.¹ For this purpose, a facile method for characterizing defect states is indispensable.² Here, we introduce a gate-modulated optical method for identifying defect states through photocurrent signatures. The DC gate voltage progressively fills defect states, while 820-nm sub-gap illumination excites electrons from the occupied defect states into the conduction band. A small AC modulation superimposed on the gate voltage periodically modulates the defect occupancy and the resulting photoinduced drain current. The measured AC response therefore represents the device transconductance, and its illumination-induced variation provides a direct signature of defect-state occupation and optical excitation.

Gate-voltage-dependent transconductance and temperature-dependent photovoltage
Figure 1 (a) Amplified transconductance in the dark and sub-gap illuminated condition showing an enhancement and dip at a specific gate voltage. (b) Temperature-dependent photovoltage shows a decrease in enhancement as temperature increases.

References

  1. W. Ren, et al., The 2D Materials Roadmap, 2D Mater. 12, (2025), DOI: 10.1088/2053-1583/ae2b82.
  2. J. Hong, Z. Hu et al., Exploring Atomic Defects in Molybdenum Disulphide Monolayers, Nat. Commun. 6, 6293 (2015), DOI: 10.1038/ncomms7293.
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