MANA International Symposium 2025


Session 5-3

Title

Nanoscale infrared spectroscopy for two-dimensional nitrides

Author's photo

Authors

Satoshi Ishii

Affiliations

Optical Nanostructure Team, MANA, NIMS

URL

https://samurai.nims.go.jp/profiles/sishii/publications?locale=en

Abstract

While infrared spectroscopy, typically using a Fourier transform infrared spectrometer (FTIR), is a powerful tool for characterizing various physical and chemical properties of samples, its spatial resolution is limited to microns due to the diffraction limit. In contrast, nano-FTIR, which combines scattering-type near-field scanning optical microscope and FTIR, offers nanoscale spatial resolution not only in the lateral direction but also in the depth direction. This is particularly suitable for characterizing two-dimensional samples. In this talk, we present our two recent examples. The first topic is the visualization of the two-dimensional electron gas (2DEG) in an AlGaN/GaN heterostructure, where the 2DEG is clearly observed in cross-sectional scanning using nano-FTIR.[1] In the second example, chemical analysis of the single-photon emitters in hBN is performed using nano-FTIR. In both cases, the nano-scale special resolution of the nano-FTIR in three dimensions is the key to obtaining results that could have been hidden in conventional FTIR.

Fig. 1. (a) Schematic showing the cross-section measurement of AlGaN/GaN by nano-FTIR. (b) Schematic showing the excitation of a single photon source in hBN and nano-FTIR measurement.

Reference

  1. I. Bisignano, M. Imura, N.K. Tanjaya, M. Ye, N. Okada, S. Ishii, ACS Appl. Mater. Inter. in press. DOI: 10.1021/acsami.5c12417