CommentFigure shows thermographs in the first and second heating processes. Sulfidation reaction starts above 360�Ž, and finishes at 690�Ž.(approximately by 90%)
The enthalpy of formation�@Product is the trigonal
ZrS2. Small impurity phase is ZrS3. The enthalpy of formation becomes ĢHf=96.3Kcal/mol.