Zr + S
Reaction Zr + 2S ¨ ZrS2
Phase transition


ReagentZr powder (3N 300mesh)

S powder (6N)
CompanyRare Metallic Co. Ltd.
Weight23.5mg
ContainerSiO2 glass, Reference SiO2 glass 410mg
Comment
Figure shows thermographs in the first and second heating processes. Sulfidation reaction starts above 360Ž, and finishes at 690Ž.(approximately by 90%)
The enthalpy of formation
@Product is the trigonal ZrS2. Small impurity phase is ZrS3. The enthalpy of formation becomes ĢHf=96.3Kcal/mol.
DSChome