Ni + S (No.1)
Reaction Ni + S ¨ Ni(1-x)S + {NiS2}
Phase transition


ReagentNi powder (3N 200mesh)

S powder (6N)
CompanyRare Metallic Co. Ltd.
Weight29.2mg
ContainerSiO2 glass, Reference material SiO2 glass 325mg
Comment
Figure shows only the first and second heating processes.
Sulfidation reaction starts at 240Ž, and finishes at 485Ž.
ĢHr=839.5J/g.
The enthalpy of formation
@Product is the hexagonal Ni(1-x)S. A little of cubic NiS2 is coexisted. If all products are NiS, the enthalpy of formation becomes ĢHf=18.2Kcal/mol.
DSChome