Hf + 2S
Reaction Hf + 2S �¨ HfS2
Phase transition


ReagentHf powder (2N6 325mesh)

S powder (6N)
CompanyRare Metallic Co. Ltd.
Weight38.4mg
ContainerSiO2 glass, Ref. material�@SiO2 glass 410mg
Comment
Figure shows the first and second heating processes. Sulfidation reaction proceeds by more than 90% over 425-650�Ž. Second curve corresponds to the back ground. ƒ¢H‚’=2.06J/g.
The enthalpy of formation
�@Product is the trigonal HfS2. A small amount of unreacted Hf is coexisted. The enthalpy of formation, ƒ¢Hf=119.1Kcal/mol
DSChome