Co + S
Reaction Co + S �¨ CoS
Phase transition


ReagentCo powder (3N 325mesh)

S powder (6N)
CompanyRare Metallic Co. Ltd.
WeightCo+S 28.4mg
ContainerSiO2 glass
Comment
Fugure shows only the heating process.�@
Sulfidation reaction starts above 300�Ž, and finishes at 510�Ž.
Exothermic peak,�@max 412�Ž�@ƒ¢Hr= -871.8 J/g�@
The enthalpy of formation�@
Products: main phase is hexagonal CoS. Coexisted phase is cubic Co9S8. Calculated enthalpy of formation of CoS is approximately ĢHf= 19.7Kcal/mol
DSChome