Comment1st and 2nd runs are shown 
However, 2nd run was measured the day after 1st run 
Reaction occurs over 525-791℃. Absorption in peak top of exothermal events corresponds to the melting of Al (660℃) 
The enthalpy of formationProduct is the tetragonal 
 Al2S3. Exothermic heat amounts to 2713J/g 
which corresponds to ΔH=114.8Kcal/mol