Ag + S
Reaction 2Ag + 2S Ag2S + S
Phase transition 186(Ag2S), 611(Ag2S)


ReagentAg powder (3N 0.3`0.7 micron)

S powder (6N)
CompanyRare Metallic Co. Ltd.
Weight43.6 mg
ContainerSiO2 glass
Comment
Only the heating and cooling one cycle is shown.
Heating processFFormation reaction is started near the melting point of Sulfur. 121 -30.96J/g Ag2S Tr 186 10.11J/g@ secondary sulfidation of residual silver 382 -79.90J/g Ag2S Tr () 611 4.14J/g
Cooling processFTr 597 -4.11J/g Tr 166@-26.53J/g @
The enthalpy of formation
Product is Ag2S. Enthalpy of reaction is H=-110.9J/g, so that the enthalpy of formation of Ag2S is@31kJ/mol
DSChome