Ag + S
Reaction 2Ag + 2S �¨ Ag2S + S
Phase transition 186�Ž(Ag2S), 611�Ž(ƒÀ�¨ƒÁAg2S)


ReagentAg powder (3N 0.3�`0.7 micron)

S powder (6N)
CompanyRare Metallic Co. Ltd.
Weight43.6 mg
ContainerSiO2 glass
Comment
Only the heating and cooling one cycle is shown.
Heating process�FFormation reaction is started near the melting point of Sulfur. 121�Ž -30.96J/g �¨ Ag2S Tr 186�Ž 10.11J/g�@�¨ secondary sulfidation of residual silver 382�Ž -79.90J/g �¨ Ag2S Tr (ƒÀ�¨ƒÁ) 611�Ž 4.14J/g
Cooling process�FTr 597�Ž -4.11J/g �¨ Tr 166�Ž�@-26.53J/g �@
The enthalpy of formation
Product is Ag2S. Enthalpy of reaction is ƒ¢H=-110.9J/g, so that the enthalpy of formation of Ag2S is�@31kJ/mol
DSChome