Quantum Material-Properties Group

We study electronic properties of materials such as superconductors and topological materials.
Electrons underlie many physical properties of materials. For example, in superconductors electrons pair and carry electricity without dissipation. Topological materials attract much attention because electrons in topologically non-trivial states may be important in future quantum information technology.
We investigate electronic properties through low-temperature high-magnetic-field measurements as well as through theoretical studies.
We are also interested in quantum vortices in superconductors.

Dirac electrons in the iron-based superconductor CaFeAsF observed via quantum oscillation measurements

In superconducting phenomena, especially in materials called high-temperature superconductors, superconductivity is generally exhibited by substituting some elements of the parent material. Therefore, it is important to elucidate the electronic state of the parent material in order to elucidate the superconducting mechanism. This time, the quantum oscillation was measured on the iron-based 1111 type parent material CaFeAsF single crystal, and the Fermi surface was successfully observed for the first time in the world.
For the 1111 type mother material, it was difficult to prepare a high-quality sample, and the experimental elucidation of the electronic state had not progressed. However, a high-quality single crystal was synthesized and measured under a strong magnetic field. The existence of Dirac electrons was clarified as predicted by theoretical analysis of the electronic structure of CaFeAsF. Dirac electrons are electrons that exist in a unique band structure called Dirac cone, and are not easily affected by impurities. This result is an important basic finding for elucidating the origin of iron-based superconductivity, and shows that iron-based superconductors can be the stage for exploring new functionality that combines the specificity and superconductivity of Dirac electrons.

Fig.1. CaFeAsF

Fig.2. Magnetoresistance(red) and its oscillatory part, Shubnikov-de Haas oscillation,(brown).

Fig.3. Fermi surface

Real spin and pseudospin topologies in the nodal-line semimetal CaAgAs observed via quantum oscillation measurements

Classification based on the topology of electronic states is a paradigm shift in material science that began in this century, and topological materials are expected to have new functionality such as quantum information processing. We are working on the identification of topological electronic states by quantum oscillation measurement. Quantum oscillation is a phenomenon in which magnetization, electrical resistance, etc. of a metal oscillate as a function of a magnetic field in an ultra-low temperature and strong magnetic field, and the Fermi surface of the metal, effective mass of electrons, etc. are determined. Recently, the phase of oscillation in CaAgAs has been analyzed. Attempts have been made to detect the Berry phase associated with the topological electronic state.
The substance targeted this time is CaAgAs (Fig. 1). Theoretically, it is predicted that the point where the energy bands of electrons intersect (when the spin-orbit coupling is ignored) forms a circle, resulting in a nodal-line semimetal. In practice, self-doping creates a donut-shaped hole around this nodal line. Furthermore, the donuts are nested because the crystal structure has no inversion symmetry and the spin degeneracy is lifted. In the experiment, the quantum oscillation appearing in the magnetic torque was measured using a dilution refrigerator and a 20T superconducting magnet. Of the four types of electron orbits that can be observed by quantum oscillation (Fig. 2), β and γ were mainly observed. The observed oscillation is a superposition of oscillations from four orbits, including a time-reversed pair of each orbit and a similar pair inside the nest. By analyzing the position of the node due to interference (Fig. 3), it was revealed that both orbits accompany the Berry phase. It was expected that β surrounding the nodal line would have a Berry phase due to the rotation of the orbital pseudospin, but the Berry phase of γ was unexpected. A closer examination by first-principles calculation revealed that the origin is that the direction of the real spin rotates along the γ orbit. Topological electronic states due to pseudospins and real spins have been studied in different materials so far, but the present study shows that they can coexist in crystals lacking inversion. The research possibility of the interplay between the two topologies are suggested.

Fig.1. (upper) Crystal structure and band structure of CaAgAs. (lower) Magnetic torque measurements using an AFM cantilever.

Fig.2. (upper) Donut-shaped Fermi surface and four kinds of cyclotron orbits. (lower) Real- and pseudo-spin textures.

Fig.3. Analysis of oscillation nodes
H.T.Hirose, T.Terashima, et al.,Phys.Rev.B101, 245104(2020)

Theoretical study on emergence and disappearance of electronic states

(1)Emergence and disappearance of electronic states in a coupled-dimer system
One of the goals of MANA is to create novel characteristics using nanoarchitectonics. Here, we considered a nanosystem
consisting of dimers, and we theoretically studied its electronic states. In the conventional band theory, there are only two
bands originating from the bonding and antibonding orbitals. However, we theoretically demonstrated that electronic states
can emerge and disappear depending on the electron density in the strongly interacting coupled-dime system. (Fig. 1)
(2) Do electrons behave as particles in materials?
Electrons in materials are considered to behave as particles with spin and charge like those in a vacuum. Based on this
picture, electrons are treated as particles moving in an effective potential created by nuclei and other electrons in the band
theory. However, electrons can lose its identity (spectral weight) while its motion is preserved in the spin degrees of freedom
in strongly interacting systems. Emergence and disappearance of electronic states cause the need for reconsideration of the
views on electrons in materials and may bring new inventions of electronic devices based on novel characteristics. (Fig. 2)

Fig.1. Evolution of electronic state and disappearance of antibonding band with electron density n.
M.Kohno, phys. Rev. B100 ( 2019 ) 235143

Fig.2. Electronic state in a vacuum (left), conventional metal (right top), and strongly interacting system (right bottom).

Vortex and Josephson junction device applications

(1) Josephson junction and superconducting quantum interference devices(SQUIDs) using boron-doped diamond superconductor  
Josephson junction and SQUIDs have been applied to ultra-sensitive quantum magnetic sensors and quantum computing. However, conventional SQUIDs have problems such as device degradation due to oxidation and mechanical destruction due to physical contact. Diamonds, on the other hand, have excellent chemical and mechanical stability and can provide robust superconducting devices. In this study, diamond Josephson junctions were developed by step-edge structure and trench structure, and we demonstrated the operation of single crystal diamond SQUIDs for the first time. We succeeded in Josephson junction operation (I-V and shapiro-step characteristics) at ~8K above the liquid helium temperature, and also produced dc SQUIDs, and succeeded in confirming the operation using a SQUID drive electronics (Fig 1).
(2) STM-SQUID hybrid magnetic microscope and magnetic flux quantum simulation 
SQUID microscopes have been developed as a tool for observing micro magnetic images on a micron- and a nano-scale. Conventional SQUID microscopes have problems such as device destruction due to contact with the sample. In this research, we have developed a microscope that achieves high sensitivity and high resolution by integrating STM and SQUID by high permeability probe and enables simultaneous measurement of surface morphologies and magnetic images. In addition to designing and implementing a microscope system that contributes to the measurement of superconducting samples at extremely low temperatures, we developed a magnetic flux quantum (vortex) and magnetic probe coupling simulation for the vortex observation (Fig 2).

Fig.1. Development of Diamond SQUID devices.
T. Kageura et al., Sci. Rev. 9, 15214(2019).

Fig.2. Development of STM-SQUID microscope and numerical simulation of vortices.

Theoretical study of charge dynamics in high-Tc cuprate superconductors

Dual structure of charge excitation spectrum
 High temperature superconductivity in cuprates is realized upon charge carrier doping into the Mott insulator. The understanding of the charge dynamics is, therefore, a vital issue to the high-Tc mechanism. Recently, advanced x-ray scattering techniques revealed the charge dynamics in momentum-energy space, providing a hot theme in the cuprate physics.
 Theoretically it is highly nontrivial to compute the charge excitation spectrum because of strong electron correlations. We employed a large-N technique formulated in the t-J model and found that the spectrum is characterized by a dual structure, consisting of qualitatively different charge excitations. One is bond-charge excitations with d-wave symmetry (Fig. 1), which is driven by the antiferromagnetic superexchange interaction. Their doping dependence (inset in Fig. 1) showed a good agreement with experimental data. The other is acoustic-like plasmon excitations originating from the long-range Coulomb interaction (left panel in Fig. 2). The acoustic-like plasmons are characterized by the unique qz dependence (right panel in Fig. 2), which serves to distinguish between different scenarios. The predicted qz dependence was indeed confirmed by experiments.

Fig.1. d-wave bond-charge excitation spectrum. A peak develops around the momentum (π/2,0) with decreasing temperature T. The Inset shows the T dependence of the peak intensity for several doping rates δ.
Yamase, Bejas, Greco, Phys. Rev. B 99, 014513 (2019)

Fig.2 (left) Acoustic-like plasmon excitations. A gap is present at (0,0). Our theoretical results (solid lines) agree with the experimental data. (right) qz dependence of the acoustic-like plasmons.
Greco, Yamase, Bejas, Commun. Phys. 2, 3 (2019)

Research on the vortex matter in superconductors

(1) Vortex states in mesoscopic-sized crystals of high-Tc superconductors
  Arrangement of small-number vortices (magnetic flux quantum) in a sufficiently small superconductor comparable to the magnetic penetration depth is influenced by a confinement effect exerted by a circulating screening current. On the other hand, high-Tc cuprate superconductors have fruitful thermodynamic vortex phase diagram, e.g., vortex liquid, vortex lattice, and 1st order melting transition. We have studied influence of the confinement on the vortex phase of high-Tc superconductors and succeed to observe the melting transition of confined vortex clusters in a tiny polygonal stack of Bi2212 intrinsic Josephson junction (Fig. 1, left). The melting transition temperature Tm oscillates with increasing the number of vortices depending on the shapes of the stacks (Fig. 1, right). In the case of the equilateral-triangle shape, an edge dislocation induced in non-matching states is related to the suppression of Tm.

(2) Magneto-optical imaging of magnetic field distribution in high-purity Nb superconductors
 Vortex behavior in high quality Nb crystals has been recognized to be important toward the improvement of superconducting acceleration cavities. Vortices that are not expelled from the inside of a bulk Nb during a cooling process become an origin of energy dissipation of RF field and affect to decrease the quality factor. We observed magnetic field distribution on the surface of cavity-grade Nb samples by magneto-optical imaging technique (Fig. 2, left) to study what kind of sites or defects trap vortices effectively. The right-top of Fig. 2 shows penetration of vortices through a grain boundary in relatively high field. NbHx precipitates nucleated around 200 K are another kind of pinning sites which cause the so-called Q-disease (right bottom of Fig. 2) .

Fig.1. Vortex states confined in high-Tc superconductor Bi2212 of mesoscopic scale. For a triangular Bi2212, see S.Ooi,et al., Phys. rev. B100, 144509 ( 2019 )

Fig.2. Magneto-optical imaging of magnetic-field distribution in Nb superconductors. Presented in a poster of ISS2019.

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Quantum Material-Properties Group
3-13 Sakura, Tsukuba, Ibaraki, 305-0003 Japan
TEL: 029-863-5510
E-Mail: TERASHIMA.Taichi=nims.go.jp(Please change "=" to "@")