August 2008 Archives
Some of the most well known self-assembled monolayers (SAMs) are alkyl sulfides on gold surfaces. They have many potential applications in molecular electronics, biosensors, and nanopatterning. However, there have still been unsolved problems in basic research regarding Au-S interaction. Recently, Professor A. Morgante (Universita' di Trieste, Italy) and his colleagues published the results of grazing incidence X-ray diffraction and density functional theory-based molecular dynamics simulations for hexanethiol and methylthiol. The research group demonstrated surface complexes wherein two S atoms are joined by an intermediate Au adatom (RS-Au-SR) for longer chain cases. It was found that the sulfur atoms of the molecules bind at two distinct surface sites, and that the first surface layer contains vacancies as well as gold adatoms that are laterally bound to two sulfur atoms. Competition between SAM ordering and disordering of interfacial Au atoms takes an important role in the system. For more information, see the paper, "X-ray Diffraction and Computation Yield the Structure of Alkanethiols on Gold(111)", A. Cossaro et al., Science, 321, 943-946 (2008).
Our lab signed a Memorandum of Understanding (MOU) for research collaboration on the X-ray physics and industrial radiography with Chalk River Laboratories, Atomic Energy of Canada Limited (AECL), Ontario, Canada. The two institutions agreed to promote exchanges of researchers, information, publication of the results of the research and/or the implementation of cooperative research. AECL is responsible for the research and development of Canada deuterium uranium (CANDU) nuclear reactors. Both sides understand the significance of novel advanced X-ray technologies for non-destructive examination.
From right to left: Dr. Dag Horn (AECL, Section Head, NDE Technologies), Dr. William Kupferschmidt (AECL, Vice-President & General Manager, R&D), Dr. Robert Tapping (AECL, Director, Components and Systems Division), Dr. Nigel Fisher (AECL, Branch Manager, IMD), Dr. Kenji Sakurai (NIMS, Group Leader, Quantum Beam Center), Dr. Krassimir Stoev (AECL, Research Scientist, NDE Section).
The 2008 Birks Award was presented to Professor Rene Van Grieken (the chief editor of X-Ray Spectrometry journal), University of Antwerp, Antwerp, Belgium
The 2008 Jerome B. Cohen Student Award was presented to Mr. Sterling Cornaby, Cornell University, Ithaca, New York, for work entitled, "Bifocal miniature toroidal shaped X-ray mirrors
The 2008 McMurdie Award was presented to Dr. Jeffrey Dann, Osram Sylvania, Towanda, PA
Proferssor Rene Van Grieken was awarded the Birks Award.
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