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Jonathan P. Hill

MANA Scientist

Affiliation:


Educational & Research History

2006 - Present
Senior Researcher, Supermolecules Group, National Institute for Materials Science.
2004
Postdoctoral Fellow, International Center for Young Scientists, National Institute for Materials Science.
2002
Postdoctoral fellow, ERATO Nanospace Project, Tokyo, Japan.
2001
Postdoctoral fellow, University of Karlsruhe, Germany.
1999
Senior Researcher, University of East Anglia, UK.
1997
STA Postdoctoral fellow, AIST Kansai, Osaka, Japan.
1995
Ph.D, Brunel University, UK.


Research


  1. Self-assembly of small molecules. Supramolecular synthesis of molecular arrays in various media including solution or at surfaces. Highlights: (a) preparation of self-assembled nanotubes with large aspect ratio and monodisperse cross-sectional diameter; (b) control of surface assembly using molecular oxidation state or hydrogen bonding.

  2. Chemistry of non-planar tetrapyrroles. Certain tetrapyrroles (porphyrins) can be synthetically manipulated through the usually inaccessible central nitrogen atoms permitting modulation of their properties. Highlights: (a) chromogenic sensing of anions; (b) poly-tautomerism in novel corrole derivatives.

  3. Nanomaterials from coordination complexes of transition elements. Coordination complexes of transition metal cations can be processed by a variety of means into materials with nanoscale structural features. Highlights: (a) thermolytic processing of dinuclear complexes of iron; (b) nanostructured microspheres of manganese oxide by room temperature solution processing.




Selected Papers

  1. 1) "Fluoride-ion-binding Promoted Photoinduced Charge Separation in a Self-assembled C60 Alkyl Cation Bound Bis-crown Ether-oxoporphyrinogen Supramolecule"
    W. A. Webre, H. B. Gobeze, S. Shao, P. A. Karr, K. Ariga, Jonathan P. Hill and F. D’Souza.
    Chem. Commun. (2018) 54, 1351–1354.
  2. 2) "Porphyrinoid Rotaxanes: Building a Mechanical Picket Fence"
    T. H. Ngo, J. Labuta, G. N. Lim, W. A. Webre, F. D’Souza, P. A. Karr, J. E. M. Lewis, Jonathan P. Hill, K. Ariga and S. M. Goldup.
    Chem. Sci. (2017) 8, 6679–6685.
  3. 3) "Substrate-mediated C-C and C-H Coupling after Dehalogenation"
    H. Kong, S. Yang, H. Gao, A. Timmer, Jonathan P. Hill, O. Díaz Arado, H. Mönig, X. Huang, Q. Tang, Q. Ji, W. Liu and H. Fuchs.
    JACS (2017) 139, 3669–3675.
  4. 4) "Mesomorphic Fluorescent Pyrazinacenes"
    G. J. Richards, S. Ishihara, J. Labuta, D. Miklik, T. Mori, S. Yamada, K. Ariga, Jonathan P. Hill.
    J. Mater. Chem. C (2016) 4, 11514–11523.
  5. 5) "Molecular Engineering Combined with Cosensitization Leads to Record Photovoltaic Efficiency for Non-ruthenium Solar Cells"
    Jonathan P. Hill.
    Angew. Chem. Int. Ed. (2016) 55, 2976–2978.
  6. 6) "A Current-driven Supramolecular Motor with In-situ Surface Chiral Directionality Switching"
    P. Mishra, Jonathan P. Hill, S. Vijayaraghavan, W. v. Rossom, S. Yoshizawa, M. Grisolia, J. Echeverria, T. Ono, K. Ariga, T. Nakayama, C. Joachim and T Uchihashi.
    Nano Lett. (2015) 15(7), 4793–4798.
  7. 7) "Chiral Sensing using Non-chiral Porphyrins"
    J. Labuta, Jonathan P. Hill, S. Ishihara, L. Hanykova, K. Ariga.
    Acc. Chem. Res. (2015) 48, 521–529.
  8. 8) "Chiral Guest Binding as a Probe of Tautomerism and Macrocyclic Inversion in a Conjugated Tetrapyrrole"
    J. Labuta, Z. Futera, S. Ishihara, H. Kourilova, Y. Tateyama, K. Ariga, Jonathan P. Hill.
    JACS (2014) 136, 2112–2118.
  9. 9) "NMR Spectroscopic Detection of Chirality and Enantiopurity in Referenced Systems without Formation of Diastereomers"
    J. Labuta, S. Ishihara, T. Šikorský, Z. Futera, A. Shundo, L. Hanyková, J. V. Burda, K. Ariga, Jonathan P. Hill.
    Nat. Commun. (2013) 4, ncomms3188.
  10. 10) "Reversible Photoredox Switching of Porphyrin-bridged Bis-2,6-di-t-Butyl Phenols"
    S. Ishihara, Jonathan P. Hill, A. Shundo, K. Ohkubo, S. Fukuzumi, M. R. J. Elsegood, S. J. Teat, K. Ariga.
    JACS (2011) 133, 16119–16126.
  11. 11) "Real time Self-assembly and Reassembly of Molecular Nanowires of Trigeminal Amphiphile Porphyrins"
    Y. Xie, M. Akada, Jonathan P. Hill, Q. Ji, R. Charvet, K. Ariga.
    Chem. Commun. (2011) 47, 2285–2287.
  12. 12) "Anion-complexation-induced Stabilization of Charge Separation"
    F. D’Souza, N. K. Subbaiyan, Y. Xie, Jonathan P. Hill, K. Ariga, K. Ohkubo, S. Fukuzumi.
    JACS (2009) 131, 16138–16146.
  13. 13) "Nuclear Magnetic Resonance Signaling of Molecular Chiral Information using an Achiral Reagent"
    A. Shundo, J. Labuta, Jonathan P. Hill, S. Ishihara, K. Ariga.
    JACS (2009) 131, 9494–9495.
  14. 14) "Pyrazinacenes: Oligoaza Analogues of Acenes"
    G. J. Richards, Jonathan P. Hill, N. K. Subbaiyan, F. D’Souza, M. R. J. Elsegood, S. J. Teat, T. Mori, K. Ariga.
    J. Org. Chem. (2009) 74, 8914–8923.
  15. 15) "Thermolysis of a Hybrid Organic-Inorganic Supramolecular Coordination Assembly: Templating the Formation of Nanostructured Fibrous Materials and C-based Microcapsules"
    W. Schmitt, Jonathan P. Hill, S. Malik, C. E. Anson, A. K. Powell.
    Angew. Chem. Int. Ed. (2005) 44, 7048–7053.
  16. 16) "Supramolecular Coordination Assemblies of Dinuclear Fe Complexes"
    W. Schmitt, Jonathan P. Hill, P. Juanico, A. Caneschi, F. Costantino, C. E. Anson, A. K. Powell.
    Angew. Chem. Int. Ed. (2005) 44, 4187–4192.
  17. 17) "Self-Assembled Hexa-peri-hexabenzocoronene Graphitic Nanotubes"
    Jonathan P. Hill, W. Jin, A. Kosaka, T. Fukushima, H. Ichihara, T. Shimomura, K. Ito, T. Hashizume, N. Ishii, T. Aida.
    Science (2004) 304, 1481–1483.
  18. 18) "Cation-π binding of an Alkali Metal Ion by Pendant α,α-Dimethylbenzyl Groups in a Mixed Metal Coordination Complex"
    W. Schmitt, C. E. Anson, Jonathan. P. Hill, A. K. Powell.
    JACS' (2003) 125, 11142–11143.
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