
An atom probe field ion microscope (APFIM) is a
combination of a field ion microscope (FIM) and a time-of-flight mass
spectrometer of a single ion sensitivity.
When high electric field is applied on a surface of a sharp needle
tip, imaging gas atoms are ionized at the protruding sites on the
surface.
These ions hit screen, forming brightly imaging spots.
Hence, the FIM is a projection
type microscope of an atomic resolution with an approximate magnification
of a few million times.
By appling higher electric filed, surface atoms of the specimen are also
ionized. By this field evaporation process, one can sample atoms of the
specimens from the surface. Measuring the time-of-flight of individual
atoms which go through a small aperture in the center of the screen
makes it possible to determine the mass to charge ratios of individual atoms.
Atoms are collected only within the aperture.
The effective size of the aperture is typically from 0.5 to 5 nm. Hence,
atom probe has a spatial resolution of this demension in the lateral direction.
Atoms always evaporate from the surface, so the spacial resolution in the
depth direction is a mono-atomic layer.
A unique feature of the atom probe compared with the other analytical
instrument is its extremely high spatical resolution and the equal detection
efficiency for light elements.
A Typical FIM Image
What is Three Dimensional Atom Probe?
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